SYNTHESIS, SPECTRAL, SOLID STATE ELECTRICAL CONDUCTIVITY AND BIOLOGICAL ACTIVITY STUDIES ON SOME THIAZOLINE -CYCLODIPHOSPH(V)AZANE METAL COMPLEXES | ||
| Al-Azhar Bulletin of Science | ||
| Article 21, Volume 2007, Issue 12, December 2007, Pages 247-261 PDF (453.61 K) | ||
| Document Type: Original Article | ||
| DOI: 10.21608/absb.2007.11154 | ||
| Authors | ||
| ABD-ELNASSER M. ALAGHAZ* 1; SALWA A. ELBOHY2 | ||
| 1Chemistry Department, Faculty of Science (Boys), Al-Azhar University, Nasr City, Cairo, Egypt. | ||
| 2Department of Chemistry, Faculty of Science, Al-Azhar University (for Girls), Nasr City, Cairo, Egypt | ||
| Abstract | ||
| Aminocyclodiphosph(V)azane of thiazoline, III (1,3-diphenyl-2,4-bis(2-acetyl-2-thiazolinehydrazone)-2,2,4,4-tetrachlorocyclodiphosph(V)azane, reacts with stoichio-metric amounts of transition metal salts such as Co(II), Ni(II), and Cu(II) to afford coloured complexes in a moderate to high yield. The structure of the isolated complexes was suggested based on elemental analyses, IR, molar conductance, UV-Vis, 1H and 31P NMR, solid reflectance, magnetic susceptibility measurements and dark electrical conductivity of solid state. The solid state electrical conductivity obtained reveals that the ligand (III) and its metal complexes behave as semiconducting materials. Most of the prepared compounds showed high bactericidal activity and, in some cases, the complexes have higher bactericidal activity than the ligand. | ||
| Keywords | ||
| cyclodiphosph(V)azane metal complexes; electronic; IR; magnetic moment; electrical conductivity | ||
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