Factors Affecting the Catalytic Hydrogenation of p-Nitrophenol by Nano Nickel Supported on Egyptian Kaolin | ||||
Egyptian Journal of Chemistry | ||||
Article 6, Volume 55, Issue 6, December 2012, Page 649-658 PDF (327.25 K) | ||||
DOI: 10.21608/ejchem.2012.1179 | ||||
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Abstract | ||||
THE LIQUID-PHASE catalytic hydrogenation of p-nitrophenol to ……p-aminophenol was studied over kaolin supported nano-nickel catalysts prepared by chemical reduction by hydrazine hydrate. It was found that the 5% Ni-K catalyst has a superior catalytic activity corresponding to the other nickel contents, and hence it was chosen for determining the optimum conditions of such reaction. The effect of catalyst loading, p-nitrophenol concentration, NaOH and NH4OH concentrations on the catalytic activity of nano-nickel catalyst was investigated at 80oC. It was assessed that the catalytic efficiency of the catalyst was enhanced considerably by changing in NaOH and NH4OH concentrations during hydrogenation reaction. | ||||
Keywords | ||||
Nano-nickel catalyst; Egyptian kaolin support and Hydrogenation | ||||
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