Synthesis, Characterization, and X-ray Crystal Structure Analysis of Zinc(II) Complex Based on 2-benzimidazolethiole | ||
| Egyptian Journal of Chemistry | ||
| Article 18, Volume 64, Issue 5, May 2021, Pages 2415-2419 PDF (499.77 K) | ||
| Document Type: Original Article | ||
| DOI: 10.21608/ejchem.2021.55124.3155 | ||
| Authors | ||
| Karwan Omer Ali* 1; Hikmat Ali Mohamad2; Eric Hosten3; Thomas Gerber3 | ||
| 1College of Science, University of Halabja, Halabja, Iraq | ||
| 2Department of Chemistry , College of Education,University of Salahaddin-Erbil-Iraq | ||
| 3Department of Chemistry, Faculty of Science, Nelson Mandela Metropolitan University, Port Elizabeth, South Africa | ||
| Abstract | ||
| A novel mononuclear complex of the type [Zn(S-2-BIT)3(O-SO3)(CH3OH)2] (where 2-BIT = 2-benzimidazolethiole) has been synthesized and characterized by elemental analysis, FT-IR spectroscopy, UV-Vis spectroscopy, and single crystal-crystal X-ray diffraction. The crystal structure of the complex show that crystallizes in the triclinic P(1 ) ̅space group, with a=9.2946(13) Å, b= 10.1997(13) Å, c= 17.345(3) Å, β=105.494(7)օ, V= 1516.3(4) Å3, R1= 0.0316, wR2= 0.0843. In this complex, the distorted tetrahedral arrangement around the Zinc(II) atom is formed by three sulfur atoms from the 2-MBI ligand and one oxygen atom from the sulfate ion. The crystal lattice structure of the complex also contains two uncoordinated methanol molecules that formed N-H...O and O-H...O intermolecular hydrogen bonds. | ||
| Keywords | ||
| Zn(II) complex; S-donor ligand; X-ray crystallography; Distorted tetrahedral coordination | ||
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