One-Pot Synthesis, Characterization, and Antibacterial Activity of Mono Azo-Disperse Dyes bearing Bis-α-Aminophosphonates moiety and their application in Polyester Printing
Rekaby, M., Elkhabiry, S., Hussein, S., Quhal, G., Qaisy, A. (2022). One-Pot Synthesis, Characterization, and Antibacterial Activity of Mono Azo-Disperse Dyes bearing Bis-α-Aminophosphonates moiety and their application in Polyester Printing. EKB Journal Management System, 65(132), 331-338. doi: 10.21608/ejchem.2022.125556.5581
Manal M. Rekaby; Shaban Elkhabiry; Salama S. Hussein; Ghada M. Quhal; Al Anood S. Qaisy. "One-Pot Synthesis, Characterization, and Antibacterial Activity of Mono Azo-Disperse Dyes bearing Bis-α-Aminophosphonates moiety and their application in Polyester Printing". EKB Journal Management System, 65, 132, 2022, 331-338. doi: 10.21608/ejchem.2022.125556.5581
Rekaby, M., Elkhabiry, S., Hussein, S., Quhal, G., Qaisy, A. (2022). 'One-Pot Synthesis, Characterization, and Antibacterial Activity of Mono Azo-Disperse Dyes bearing Bis-α-Aminophosphonates moiety and their application in Polyester Printing', EKB Journal Management System, 65(132), pp. 331-338. doi: 10.21608/ejchem.2022.125556.5581
Rekaby, M., Elkhabiry, S., Hussein, S., Quhal, G., Qaisy, A. One-Pot Synthesis, Characterization, and Antibacterial Activity of Mono Azo-Disperse Dyes bearing Bis-α-Aminophosphonates moiety and their application in Polyester Printing. EKB Journal Management System, 2022; 65(132): 331-338. doi: 10.21608/ejchem.2022.125556.5581

One-Pot Synthesis, Characterization, and Antibacterial Activity of Mono Azo-Disperse Dyes bearing Bis-α-Aminophosphonates moiety and their application in Polyester Printing

Egyptian Journal of Chemistry
Volume 65, Issue 132, December 2022, Page 331-338  XML PDF (894.74 K)
Document Type: Original Article
DOI: 10.21608/ejchem.2022.125556.5581
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Authors
Manal M. Rekaby email orcid 1; Shaban Elkhabiry2; Salama S. Hussein3; Ghada M. Quhal1; Al Anood S. Qaisy1
1Chemistry Department, University College of Samtah, Jazan University, Saudi Arabia
2Dyeing, Printing and Textile Auxiliaries Department, Textile Research Division National Research Centre, Dokki, Giza 12622, Egypt.
3Department of Botany, Faculty of Sscience, Menoufia University
Abstract
The synthesis of isatin hydrazide have been done in high yields at room temperature starting from indoledione (Isatin) and hydrazine hydrate. A one –pot three component Kabachnik Fields reaction was used to synthesize mono and di-α- aminophosphonate system using mono and dialdehydes containing isatin hydrazide and triethyl phosphite in methylene chloride⁄ DMF mixture using Cupper triflate as Lewis acid catalyst. The structure of those aminophosphonate derivatives have been confirmed by elemental analysis and by FT-IR, NMR spectral analysis. Mono- α-aminophosphonates azo dyes have additionally been efficaciously applied to make printing pastes for polyester fabric. The color strength and fastness properties of the printed fabrics- to washing, perspiration, and light- demonstrated moderate to excellent results. Those derivatives as well as their printed samples showed high antibacterial activities against Staphylococcus aureus (Gram +ve) and Pseudomonas auroginosa (Gram -ve) and Candida albicans (yeast) at low concentrations (2.5–10 mg /mL).
Keywords
isatin hydrazide; Cupper triflate; mono and bis aminophosphonates; Textile printing; Azo disperse dyes; antibacterial activity
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