Facile synthesis of functional heterocycles utilizing activated Benzylideneacetones | ||||
| Egyptian Journal of Chemistry | ||||
| Volume 66, Issue 13, December 2023, Page 861-867 PDF (389.56 K) | ||||
| Document Type: Original Article | ||||
| DOI: 10.21608/ejchem.2023.189232.7501 | ||||
 View on SCiNiTO | ||||
| Authors | ||||
Hoda Sabry Othman1; Khlood AbdEl-Zaher2; Marwa Mohamed Fouad 3; Galal Abd El-Moein Nawwar  4
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| 1Green Chemistry department, National research centre | ||||
| 2Green chemistry Department, chemical industries Division, National Research Centre, 33 El Bohouth St. (former El-Tahrir St.), Dokki, Giza P.O. 12622, Cairo, Egypt | ||||
| 3Basic Sciences Department, Modern Academy for Engineering &Technology, Cairo, Egypt, | ||||
| 4Green chemistry department, National Research Centre | ||||
| Abstract | ||||
| The utility of cinnamoylacetonitrile and chloroacetylcinnamates, as activated benzylideneacetones, in facile synthesis of difficulty accessible functional pyridines, furans and pyrans is presented here. Biomass-derived chemicals as furfural, gallic, benzoic, cinnamates, and acetone derivatives were used. The structures of all new synthesized compounds were confirmed on the basis of spectral analysis, IR, 1H NMR, 13C NMR, and MS spectroscopy. | ||||
| Keywords | ||||
| Benzylideneacetone; Biomass-derived chemicals; Ylide; Heterocycles | ||||
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