Outstanding Styrene-Butadiene Rubber Composites Enhanced by Surface-Modified Fillers | ||||
| Egyptian Journal of Chemistry | ||||
| Volume 67, Issue 12, December 2024, Page 451-464 PDF (6.49 MB) | ||||
| Document Type: Original Article | ||||
| DOI: 10.21608/ejchem.2024.323463.10503 | ||||
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| Authors | ||||
Salwa H. El-Sabbagh  1; Mohamed M. Selim2; Gamal Abd El-Naeem3; Doaa Samir Mahmoud1; Amir A. Abdelsalam4
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| 1Polymers and Pigments Department, National Research Centre, Cairo 12311, Egypt | ||||
| 2Physical Chemistry Department, National Research Centre, Cairo 12311, Egypt | ||||
| 3Polymer Materials Research Department, City for Scientific Research and Technology Applications, New Borg El-Arab City 21934, Alexandria, Egypt | ||||
| 4Mechanical Engineering Department, Benha Faculty of Engineering, Benha University, Benha 13511, Egypt | ||||
| Abstract | ||||
| The research findings on the mechanical properties of styrene-butadiene rubber (SBR) composites, particularly the impact of aging temperatures, have practical implications. To evaluate this effect, the study used a thermal aging test at various temperatures. The work developed SBR filled with several fillers, including kaolin, metakaolinite, zeolite Na-A, Al2O3, and synthetic zeolite Na-A/Al2O3 nanoparticles. A hybridization of SBR-filled synthetic zeolite Na-A/ Al2O3 composite was also created. The rubber mixer of two-roll mill was used to compound the material, with a filler loading of 1-5 phr. The mechanical properties of the elastomeric composites were determined before and after thermal-oxidative aging using an air-circulating oven. The respective composites were tested at varied aging times. A thermogravimetric analyzer (TGA) was used to measure thermal stability. The surface morphology of broken rubber composites was examined using a scanning electron microscope (SEM). Here, a comparative there is a comparative study of the Cross-link density estimations of cured SBR utilizing swelling and Mooney-Rivlin methods. The data from different comparison approaches yielded similar results, giving us considerable confidence in our research. Aging studies revealed that zeolite Na-A/Al2O3/SBR composite showed superior anti-aging properties in comparison to the other composite. The most effective, straightforward, and environmentally friendly technique for determining the Cross-link density of cured rubber was found to be the Mooney-Rivlin equation. Our research methods are more trustworthy because this process is based on mathematics and doesn't involve any hazardous chemicals or solvents. This study recommends using zeolite Na-A/Al2O3 as a cost-saving filler in SBR composites, which has practical implications for the industry. | ||||
| Keywords | ||||
| Thermal Aging; Thermogravimetric analysis; Treated filler; SBR composites; Tensile Properties | ||||
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