Comprehensive corrosion evaluation of sintered Al/Ni-SiC composite by CuL2 nanocomplex as a green inhibitor in 1M HCl solution | ||||
| Egyptian Journal of Chemistry | ||||
| Volume 68, Issue 6, June 2025, Page 289-311 PDF (2.55 MB) | ||||
| Document Type: Original Article | ||||
| DOI: 10.21608/ejchem.2024.312822.10207 | ||||
 View on SCiNiTO | ||||
| Authors | ||||
shimaa Abolkassem1; Lamiaa Z Mohamed   2; Shimaa Hosny 3; Omayma Ahmed El kady4; Ayman Elsayed1; Ghalia A. Gaber 5
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| 1Powder Technology Division, Manufacturing Technology Institute, Central Metallurgical Research and Development Institute, Helwan El-Tabbin, P.O. Box 87, Cairo, Egypt | ||||
| 2Mining, Petroleium, Metallurgical Engineering Dept., Faculty of Engineering, Cairo Univerrsity | ||||
| 3Chemistry Department, Faculty of Science, New Valley University, El-Kharga, 72511, Egypt | ||||
| 4Powder Metallurgy Division, Manufacturing Department, Central Metallurgical R&D Institute, P.O.87 Helwan, 11421 Cairo, Egypt. | ||||
| 5Faculty of science, chemistry department, Al Azhar University | ||||
| Abstract | ||||
| The corrosion performance of Al/Ni-SiC composites prepared by powder technology using both vacuum and hot compaction techniques for the sintering process is explored, highlighting the importance of their electrochemical and chemical properties. The research also examines the corrosive effects on aluminum metal matrix composites (AMMCs) and other solid wastes. Although AMMCs demonstrate strong mechanical and tribological properties, their corrosion resistance remains a challenge. The CuL2 nanocomplex (green nanocomplex) is prepared in a simple, rapid, and eco-friendly manner using coriandrum sativum extract in ethanol, which is employed to enhance the corrosion resistance of Al/Ni-SiC composites. Additionally, the corrosion behavior of Al/Ni-SiC composites with the CuL2 nanocomplex has been theoretically investigated using density functional theory. The investigation demonstrated that the samples with the lowest corrosion rate (CR) values were consolidated using hot compaction and vacuum mixing. The CR decreased with increasing concentrations (5%, 10%, and 15%) of nickel-coated SiC particles by weight. Specifically, the nickel-coated SiC particles in the hot compaction mix and vacuum mix at 15% in 1M HCl exhibited CR values of 1.17 mm/y and 0.39 mm/y, respectively. | ||||
| Keywords | ||||
| Al/Ni-SiC Composite, Synergistic CuL2 nanocomplex; Corrosion inhibition; Electrochemical Techniques; Density functional theory | ||||
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