Synthesis, and characterization of new Cd2+, Hg2+ complexes of thiosemicarbazone ligand derived from beta hydroxy carbonyl. | ||
| Mansoura Journal of Chemistry | ||
| Volume 61, Issue 3, May 2023, Pages 38-44 PDF (1.26 M) | ||
| Document Type: Original Article | ||
| DOI: 10.21608/mjcc.2023.411553 | ||
| Authors | ||
| Ibrahim A. Abdelwahed* 1; Gaber M. Abu El-Reash1; Magdy M. Youssef2 | ||
| 1Chemistry Department, Faculty of Science, Mansoura University, Mansoura | ||
| 2Chemistry Department, Faculty of Science, Mansoura University | ||
| Abstract | ||
| In this work, new Cd2+, and Hg2+ complexes of 4-pyridyl thiosemicarbazon Schiff base derived from beta-hydroxy carbonyl has been synthesized and isolated. The structure of the new complexes was proposed by numerous techniques such as elemental (CHN) analyses, FT-IR. TG and DTG thermal decomposition for Cd2+ complex was carried out. Thermodynamic and kinetic parameters were calculated via Coats-Redfern and Horowitz-Metzger equations. And finally, the modeling using DFT calculations was fully studied. | ||
| Keywords | ||
| 4-pyridyl thiosemicarbazon; DFT; beta-hydroxy carbonyl | ||
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