Cyclic Voltammetry of Aqueous CdSO4- N-(benzol [d] thiazol-2-yl)-3-(2-hydroxybenzylidene) hydrazinyl)-3-oxopropanamide (H2BTHB) System at 291.15 K in 50% DMSO-H2O (V/V)
Abdel-Shafy, A., Gomaa, E., Zaky, R., Hassan, N. (2021). Cyclic Voltammetry of Aqueous CdSO4- N-(benzol [d] thiazol-2-yl)-3-(2-hydroxybenzylidene) hydrazinyl)-3-oxopropanamide (H2BTHB) System at 291.15 K in 50% DMSO-H2O (V/V). EKB Journal Management System, 54(4), 6-11. doi: 10.21608/mjcc.2021.412837
Aya A. Abdel-Shafy; Esam A. Gomaa; Rania R. Zaky; Nermeen M. Hassan. "Cyclic Voltammetry of Aqueous CdSO4- N-(benzol [d] thiazol-2-yl)-3-(2-hydroxybenzylidene) hydrazinyl)-3-oxopropanamide (H2BTHB) System at 291.15 K in 50% DMSO-H2O (V/V)". EKB Journal Management System, 54, 4, 2021, 6-11. doi: 10.21608/mjcc.2021.412837
Abdel-Shafy, A., Gomaa, E., Zaky, R., Hassan, N. (2021). 'Cyclic Voltammetry of Aqueous CdSO4- N-(benzol [d] thiazol-2-yl)-3-(2-hydroxybenzylidene) hydrazinyl)-3-oxopropanamide (H2BTHB) System at 291.15 K in 50% DMSO-H2O (V/V)', EKB Journal Management System, 54(4), pp. 6-11. doi: 10.21608/mjcc.2021.412837
Abdel-Shafy, A., Gomaa, E., Zaky, R., Hassan, N. Cyclic Voltammetry of Aqueous CdSO4- N-(benzol [d] thiazol-2-yl)-3-(2-hydroxybenzylidene) hydrazinyl)-3-oxopropanamide (H2BTHB) System at 291.15 K in 50% DMSO-H2O (V/V). EKB Journal Management System, 2021; 54(4): 6-11. doi: 10.21608/mjcc.2021.412837

Cyclic Voltammetry of Aqueous CdSO4- N-(benzol [d] thiazol-2-yl)-3-(2-hydroxybenzylidene) hydrazinyl)-3-oxopropanamide (H2BTHB) System at 291.15 K in 50% DMSO-H2O (V/V)

Mansoura Journal of Chemistry
Volume 54, Issue 4, December 2021, Page 6-11  XML PDF (1.17 MB)
DOI: 10.21608/mjcc.2021.412837
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Authors
Aya A. Abdel-Shafy* ; Esam A. Gomaa; Rania R. Zaky; Nermeen M. Hassan
Chemistry Department, Faculty of Science, Mansoura University, Mansoura, Egypt
Abstract
The electrochemical behavior of cadmium ions on glassy carbon electrodes in two-step processes involves reduction at -0.95V and oxidation at -0.6 VVs. Ag/AgCl electrodes has been reported. The cyclic voltammetry data for cadmium ions using potassium chloride as supporting electrolyte in 50 % Demso-H2O (V/V) shows enhanced currents in the absence and presence of ligand N-(benzol [d] thiazol-2-yl)-3-(2-hydroxybenzylidene) hydrazinyl)-3-oxopropanamide(H2BTHB). Different cyclic voltammetry solvation data were obtained for cadmium ions in the absence and presence of (H2BTHB).The obtained cyclic voltammetry and thermodynamic data prove the complexation reaction between the cadmium ions and the used ligand.
Keywords
Cyclic voltammetry; Redox reaction; Electron rate constant; Thermodynamic; kinetic parameters
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