Synthesis and Application of Carbohydrazides Modified Cellulose for Selective Separation of Hg2+ from different municipality Samples | ||||
| Mansoura Journal of Chemistry | ||||
| Volume 48, Issue 2, May 2020, Page 21-30 PDF (992.5 K) | ||||
| Document Type: Original Article | ||||
| DOI: 10.21608/mjcc.2020.412875 | ||||
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| Authors | ||||
Magda A Akl  1; El-Sayed R. H. El-Gharkawy2; Abdelrahman S. Elzeny2; Mohamed A. Hashem2
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| 1Chemistry Department, Faculty of Science, Mansoura University 355516, Mansoura,Egypt | ||||
| 2Department of Chemistry, Faculty of Science, Mansoura University, Mansoura 35516, Egypt | ||||
| Abstract | ||||
| Carbohydrazides functionalized cellulose (CH-MC). was prepared and characterized using some qualified techniques such as Scanning Electron Microscopy (SEM), Infra-Red (FT-IR), Elemental analysis (EA). The prepared CH-MC was employed for uptake of heavy metal ions such as, Hg2+ from different samples. Sorption parameters: such as time of sorption, pH, temperature and the concentration of sorbent were investigated to determine the best conditions for sorption. The kinetic of sorption agreed with the second-order model and the chemical adsorption is the rate-limiting step. In addition, the sorption isotherm experiments revealed that the best adequate with Langmuir model sorption uptake of (CH-MC) were 64 mg. g-1 for Hg2+. The real samples including Hg2+ were used for analytical applications on the present methodology and the observed data is promising | ||||
| Keywords | ||||
| Carbohydrazides functionalized cellulose (CH-MC). Carbohydrazides; Removal of metal cations | ||||
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