Advanced Pyrano[2,3-c]Pyrazole-Based Azo Dyes: Enhanced Dyeing Performance and Antibacterial Activity of wool, polyester and nylon fabics via Gold Nanoparticle Functionalization

Ibrahim, Hassan M.; Abd El-magied, Saadia Abd El-Raoof; Mohamed, Fatma A.; Aboelenien, Mohamed Gamal

doi:10.21608/ejchem.2025.366717.11436

	Advanced Pyrano[2,3-c]Pyrazole-Based Azo Dyes: Enhanced Dyeing Performance and Antibacterial Activity of wool, polyester and nylon fabics via Gold Nanoparticle Functionalization
Egyptian Journal of Chemistry
Articles in Press, Accepted Manuscript, Available Online from 18 May 2025
Document Type: Original Article
DOI: 10.21608/ejchem.2025.366717.11436
View on SCiNiTO
Authors
Hassan M. Ibrahim ¹; Saadia Abd El-Raoof Abd El-magied²; Fatma A. Mohamed ³; Mohamed Gamal Aboelenien ⁴
¹Textile Research Division, National Research Centre, 33 El Bohouthst. (Former El Tahrir St.), Dokki, Giza, Egypt, P.O.12622
²National Research Center (NRC)
³Textile Research and technology Institute, National Research Center 33 El Buhouth St., Dokki, Giza, Egypt Postal code: 12311
⁴Gamal Abdelnaser
Abstract
Pyrano[2,3-c]pyrazole-based azo dyes have attracted considerable interest due to their vibrant coloration, chemical stability, and versatile applications. This study reports the synthesis, characterization, and performance evaluation of novel pyrano[2,3-c]pyrazole-based azo dyes (M1-M3). Compound M2 was further functionalized with gold nanoparticles (AuNPs) to enhance its dyeing efficiency and antibacterial properties. The structures of all synthesized dyes were confirmed via elemental analysis, FT-IR, NMR, and mass spectrometry. These dyes were applied to wool, polyester, and nylon fabrics using optimized dyeing techniques, including high-temperature and high-pressure (HTHP) methods. Color strength (K/S values) and fastness properties—including resistance to light, rubbing, washing, and perspiration—were comprehensively evaluated. Notably, the AuNP-functionalized M2 demonstrated superior antibacterial activity against both Escherichia coli (Gram-negative) and Staphylococcus aureus (Gram-positive), establishing it as a promising candidate for multifunctional textile applications. These findings highlight the synergistic benefits of combining nanotechnology with organic dye chemistry, providing valuable insights for developing advanced functional textiles with enhanced aesthetic and bioactive properties.
Keywords
Pyrano[2; 3-c]pyrazole; Azo dyes; Gold nanoparticles; Antibacterial textiles; Dyeing performance; High-temperature dyeing


Statistics Article View: 172