Chemical Modification of Natural Dyes: Enhancing Performance and Sustainability in Textile Applications | ||||
| Egyptian Journal of Chemistry | ||||
| Articles in Press, Accepted Manuscript, Available Online from 29 August 2025 | ||||
| Document Type: Original Article | ||||
| DOI: 10.21608/ejchem.2025.397917.11966 | ||||
 View on SCiNiTO | ||||
| Authors | ||||
Fatmaa M. Ahmed1; El-Sayed El-Shahat1; Hanan Othman2; Amina L. Mohamed   3
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| 1Textile Printing, Dyeing and Finishing Department, Faculty of Applied Arts, Tanta University, Tanta, Egypt | ||||
| 2Textile Printing, Dyeing and Finishing Department, Faculty of Applied Arts, Benha University, Benha, Egypt | ||||
| 3Pre-treatment and Finishing of Cellulose-based Textiles Department, Textile Research and Technology Institute, National Research Centre, 33 El- Behouth St., Dokki, Giza, Egypt, P.O.12622. | ||||
| Abstract | ||||
| This review examines the chemical modification of natural dyes to enhance their performance and sustainability for textile appli-cations. Natural dyes offer environmental benefits but face challenges in color fastness, substrate compatibility, and commercial viability compared to synthetic dyes. Chemical modification techniques like functional group substitution, polymer grafting, and nanoencapsulation can improve the stability, fiber affinity, and functionality of natural dyes. Semi-synthetic approaches combin-ing natural and synthetic components show promise for balancing sustainability and performance. Key modification strategies aim to enhance dye-fiber interactions, adjust solubility, modify color properties, and introduce novel functionalities like antimi-crobial or UV-protective effects. While challenges remain, dye modification enables the development of more sustainable color-ants that maintain the benefits of natural dyes while addressing their limitations for industrial use. This review highlights the potential of chemically modified natural dyes to advance more environmentally-friendly practices in textile coloration. Dye modi-fication refers to the physical or chemical modification of dyes to improve their stability, performance, and suitability for use in various contexts and materials. It is essential for solving today's textile coloring issues, such as low fastness, limit substrate compatibility, and environmental toxicity. It is possible to modify dyes by molecular engineering to have greater light and wash fastness, stronger fiber bonds, and less of an adverse environmental effect. Functional group substitution, polymer grafting, and nano-encapsulation are examples of advanced modification techniques. These methods make it possible to create smart dyes with characteristics including antibacterial activity, UV responsiveness, and temperature sensitivity. Additionally, by lowering the requirement for hazardous auxiliaries like mordants and eliminating dye loss during processing, dye modification supports sus-tainable practices. By increasing their endurance and expanding their range of applications, it also makes it possible to reuse natu-ral dyes. . The basic distinctions between natural and synthetic dyes are also examined in this article, along with their histories, characteristics and uses. This comparative research highlights the significance of innovation in dye chemistry as well as the trade-offs between sustainability and performance. The goal of dye modification is to achieve a balance between safety, durability, and beauty. According to the article's conclusion, hybrid dyeing techniques that incorporate the benefits of both dye types will be the way of the future, fostering environmentally friendly but highly effective textile solutions. | ||||
| Keywords | ||||
| Natural Dyes; Azodyes; classification; application | ||||
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