Metal complexes of new pyrimidine azodye ligands synthesis, spectral studies, thermal analysis, X-ray diffraction and uses in ink synthesis.
HASSAN, A., NASSAR, A., ABO ZAID, Y., ABD EL-RAHMAN, N., ABO ALI, M., KEHELA, T. (2011). Metal complexes of new pyrimidine azodye ligands synthesis, spectral studies, thermal analysis, X-ray diffraction and uses in ink synthesis.. EKB Journal Management System, 2011(12), 1-16. doi: 10.21608/absb.2011.7012
Ali M. HASSAN; A. M. NASSAR; Y. ABO ZAID; N. ABD EL-RAHMAN; M. ABO ALI; T. M. KEHELA. "Metal complexes of new pyrimidine azodye ligands synthesis, spectral studies, thermal analysis, X-ray diffraction and uses in ink synthesis.". EKB Journal Management System, 2011, 12, 2011, 1-16. doi: 10.21608/absb.2011.7012
HASSAN, A., NASSAR, A., ABO ZAID, Y., ABD EL-RAHMAN, N., ABO ALI, M., KEHELA, T. (2011). 'Metal complexes of new pyrimidine azodye ligands synthesis, spectral studies, thermal analysis, X-ray diffraction and uses in ink synthesis.', EKB Journal Management System, 2011(12), pp. 1-16. doi: 10.21608/absb.2011.7012
HASSAN, A., NASSAR, A., ABO ZAID, Y., ABD EL-RAHMAN, N., ABO ALI, M., KEHELA, T. Metal complexes of new pyrimidine azodye ligands synthesis, spectral studies, thermal analysis, X-ray diffraction and uses in ink synthesis.. EKB Journal Management System, 2011; 2011(12): 1-16. doi: 10.21608/absb.2011.7012

Metal complexes of new pyrimidine azodye ligands synthesis, spectral studies, thermal analysis, X-ray diffraction and uses in ink synthesis.

Al-Azhar Bulletin of Science
Article 1, Volume 2011, Issue 12, December 2011, Page 1-16  XML PDF (299.08 K)
Document Type: Original Article
DOI: 10.21608/absb.2011.7012
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Authors
Ali M. HASSAN* 1; A. M. NASSAR1; Y. ABO ZAID2; N. ABD EL-RAHMAN2; M. ABO ALI2; T. M. KEHELA1
1Chemistry Department, Faculty of Science Al-Azhar University, Cairo, Egypt.
2Chemistry Department, Faculty of Science Al-Azhar University, Cairo, Egypt
Abstract
Novel azodye ligands 2-Amino-3- (4-chloro phenylazo )-7-(4-fluorophenyl)-5-(thiophen-2-yl)-6,7-dihydropyrazolo (1,5-a) pyrimidine ( L1 ) and 2-Amino-3- (4-chlorophenylazo )-5,7-Di(thiophen-2-yl)-6,7-dihydropyrazolo(1,5-a) pyrimidine ( L2 ) and their complexes with Fe (III) , Co (II), Ni (II) and Cu (II) have been synthesized. The stereochemistry and the mode of bonding of the complexes were achieved based on elemental analysis , IR, UV-Vis, 1HNMR, MS and ESR spectroscopy as well as (TGA). Octahedral structure proposed for geometry of the chelates based on their electronic spectra and magnetic susceptibility. The metal complexes show no bleeding and tinting strength properties for ink synthesis.
Keywords
Metal complexes; pyrimidine azodye ligands; ink synthesis
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