Polymer Complexes. LVI. Supramolecular Architectures Consolidated by Hydrogen Bonding and p-p Interaction.
El-Sonbati, A., Diab, M., Belal, A., Attallah, M. (2020). Polymer Complexes. LVI. Supramolecular Architectures Consolidated by Hydrogen Bonding and p-p Interaction.. EKB Journal Management System, 35(2), 12-21. doi: 10.21608/bfemu.2020.124651
A. Z. El-Sonbati; M. A. Diab; A. A. M. Belal; M. E. Attallah. "Polymer Complexes. LVI. Supramolecular Architectures Consolidated by Hydrogen Bonding and p-p Interaction.". EKB Journal Management System, 35, 2, 2020, 12-21. doi: 10.21608/bfemu.2020.124651
El-Sonbati, A., Diab, M., Belal, A., Attallah, M. (2020). 'Polymer Complexes. LVI. Supramolecular Architectures Consolidated by Hydrogen Bonding and p-p Interaction.', EKB Journal Management System, 35(2), pp. 12-21. doi: 10.21608/bfemu.2020.124651
El-Sonbati, A., Diab, M., Belal, A., Attallah, M. Polymer Complexes. LVI. Supramolecular Architectures Consolidated by Hydrogen Bonding and p-p Interaction.. EKB Journal Management System, 2020; 35(2): 12-21. doi: 10.21608/bfemu.2020.124651

Polymer Complexes. LVI. Supramolecular Architectures Consolidated by Hydrogen Bonding and p-p Interaction.

MEJ- Mansoura Engineering Journal
Article 10, Volume 35, Issue 2, June 2010, Page 12-21  XML PDF (981.94 K)
Document Type: Research Studies
DOI: 10.21608/bfemu.2020.124651
View on SCiNiTO View on SCiNiTO
Authors
A. Z. El-Sonbati email 1; M. A. Diab1; A. A. M. Belal2; M. E. Attallah1
1Chemistry Department, Faculty of Science (Demiatta), Mansoura University, Demiatta, Egypt.
2Chemistry Department, Faculty of Science, Port Said University, Egypt
Abstract
In this study, amidation of aliphatic amine with acryloyl chloride in the dry benzene as solvent has been prepared. Moreover, the polymer complexes have been prepared. All compounds have been characterized by the analytical, spectroscopic ( IR, UV, NMR, ESR) and thermal methods. Addition, the magnetic susceptibility and molar conductance measurements have been made. Acryloylhydrazin (AH) has been shown to behave as a bidentate logand via its nitrogen (of the NH; of hydrazine group) and C-O/ C=0 (of the acryloyl group) in polymer complexes, all of which exhibit supramolecular architectures assembled through weak interaction including hydrogen bonding and 1- 1 stacking The magnetic and spectral data indicate a square planar geometry for Cu2+ complex and an octahedral geometry for Co(II) and UO2 (II). The ESR spectral data of the Cu(II) complexes showed that the metal-ligand bonds have considerable covalent character. The thermal stability was investigated using thermogravimetric analysis. The results showed that the polymer complexes are more stable than the homopolymer.
Keywords
Poly(acryloylhydrazin) homopolymer; Supramolecular polymer complexes; and thermal analysis
Statistics
Article View: 125
PDF Download: 155