Synthesis, Spectroscopic characterization and bactericidal valuation of some metal (II) complexes with new Tridentate Heterocyclic Azo Ligand Type (NNO) Donor
Hameed, G., Wadday, F., Farhan, M., Hussain, S. (2021). Synthesis, Spectroscopic characterization and bactericidal valuation of some metal (II) complexes with new Tridentate Heterocyclic Azo Ligand Type (NNO) Donor. EKB Journal Management System, 64(3), 1333-1345. doi: 10.21608/ejchem.2020.49716.3034
Ghusoon Faidhi Hameed; Fawzi Wadday; Murtadha Abd Ali Farhan; Sahar Aqeel Hussain. "Synthesis, Spectroscopic characterization and bactericidal valuation of some metal (II) complexes with new Tridentate Heterocyclic Azo Ligand Type (NNO) Donor". EKB Journal Management System, 64, 3, 2021, 1333-1345. doi: 10.21608/ejchem.2020.49716.3034
Hameed, G., Wadday, F., Farhan, M., Hussain, S. (2021). 'Synthesis, Spectroscopic characterization and bactericidal valuation of some metal (II) complexes with new Tridentate Heterocyclic Azo Ligand Type (NNO) Donor', EKB Journal Management System, 64(3), pp. 1333-1345. doi: 10.21608/ejchem.2020.49716.3034
Hameed, G., Wadday, F., Farhan, M., Hussain, S. Synthesis, Spectroscopic characterization and bactericidal valuation of some metal (II) complexes with new Tridentate Heterocyclic Azo Ligand Type (NNO) Donor. EKB Journal Management System, 2021; 64(3): 1333-1345. doi: 10.21608/ejchem.2020.49716.3034

Synthesis, Spectroscopic characterization and bactericidal valuation of some metal (II) complexes with new Tridentate Heterocyclic Azo Ligand Type (NNO) Donor

Egyptian Journal of Chemistry
Article 23, Volume 64, Issue 3, March 2021, Page 1333-1345  XML PDF (1.25 MB)
Document Type: Original Article
DOI: 10.21608/ejchem.2020.49716.3034
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Authors
Ghusoon Faidhi Hameedorcid 1; Fawzi Wadday email orcid 2; Murtadha Abd Ali Farhan1; Sahar Aqeel Hussainorcid 3
1Department of Chemistry, College of Education, University of Al-Qadisiyah, Qadisiyah, Iraq
2Chemistry Department, Science of College, Kufa of University, Al-Najaf, Iraq
3Department of Pharmaceutical Chemistry, Faculty of Pharmacy, Kufa University, Al-Najaf-Iraq
Abstract
Abstract
In this article, a synthesized ligand [(1-phenyl-2-pyrazolin-5-one) azo (6-bromo-2-hydroxynaphthalen-1-yl)] has employed for preparing three new complexes of Co(II), Ni(II) and Cu(II). The new azo ligand (PABH) has analyzed by Micro Elemental Analysis (CHNO), UV-visible, Fourier Transform infrared (FTIR) approaches, 1H,13C-NMR spectroscopy and mass spectroscopy. The consequence has specified that the ligand was represented as N,N,O-tridentate. The preparing of complexes has accomplished after fixing the finest concentration and pH values. UV-Vis spectra of these complexes solutions have been examined for a range of pH (5-9) and concentration (1×10-4 - 5×10-4) Molar that comply with Lambert-Beers law. A stoichiometry of the complexes has comprehended in relation to mole ratio which has investigated from a spectroscopic technique. The ratio of metal: ligand was achieved with (1:2) for all complexes. The metal ions complexes were characterized by FTIR, UV-Visible, molar conductance, atomic absorption, magnetic susceptibility and elemental analysis CHNO techniques. From the results of physico-chemical and spectral techniques, octahedral geometry has been proposed for these metal complexes. All these compounds were evaluated against two kinds of human pathogenic bacteria such as Staphylococcus aureus (Gram Positive) and Escherichia coli (Gram negative).
Keywords
Spectral studies; Complexes; Azo; Antimicrobial activity; Mass spectroscopy
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