Copper and silver- (N,N′- bis [2-hydroxy-1- naphthylmethylidene] -1,2-diaminoethane) complexes as efficient catalysts for the formation of 1,4-disubstituted triazoles. | ||||
Delta Journal of Science | ||||
Article 13, Volume 38, Issue 2, December 2017, Page 275-284 PDF (2.03 MB) | ||||
Document Type: Research and Reference | ||||
DOI: 10.21608/djs.2017.139874 | ||||
View on SCiNiTO | ||||
Authors | ||||
Safaa Eldin H. Etaiw; Mohamed B. Elzarie; Marwa M. Rashad | ||||
Department of Chemistry, Faculty of Science, University of Tanta, 31527-Tanta, Egypt | ||||
Abstract | ||||
The reactions of copper and silver ions with N,N’-bis(2-hydroxy-1-naphthylmethylidene)- 1,2-diamino ethane (H2L) afford the complexes [CuL], 1 and [AgHL], 2. H2L and the complexes 1 and 2 were investigated by elemental analyses, molar conductance and spectral measurements. The elemental analysis data suggest the stoichiometric ratio 1:1 [M:L]. The molar conductance measurements reveal the presence of non-electrolytic nature of the complexes. Spectral data indicated the versatility of H2L as tetra-dentate ligand via NONO with Cu and Ag atoms forming square planar and tetrahedral geometries, respectively. These complexes have good catalytic activity in click reactions to prepare 1-benzyl -4- bromo triazole and 1-benzyl-4-phenyl triazole.Key words: click reaction, Cupper, Silver, supramolecular polymers, Catalysis. | ||||
Keywords | ||||
Schiff base; Cupper; Silver; Complexes; Catalysis; Click reactions | ||||
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