Synthesis and characterization of Zn(II), Cu(II), Co(II), Ni(II), Cd(II) and Ru(III) ions with a tridentate NNO thiazole derived Schiff base
El-Medanib, S., Abdel Aaziza, A., Mohamed, R., Makhlouf, A., Mosad, S. (2017). Synthesis and characterization of Zn(II), Cu(II), Co(II), Ni(II), Cd(II) and Ru(III) ions with a tridentate NNO thiazole derived Schiff base. EKB Journal Management System, 34(part1), 510-525. doi: 10.21608/jsrs.2018.14704
Samir M. El-Medanib; Ayman A. Abdel Aaziza; Rania G. Mohamed; Abdelmoneim A. Makhlouf; Sherin A. Mosad. "Synthesis and characterization of Zn(II), Cu(II), Co(II), Ni(II), Cd(II) and Ru(III) ions with a tridentate NNO thiazole derived Schiff base". EKB Journal Management System, 34, part1, 2017, 510-525. doi: 10.21608/jsrs.2018.14704
El-Medanib, S., Abdel Aaziza, A., Mohamed, R., Makhlouf, A., Mosad, S. (2017). 'Synthesis and characterization of Zn(II), Cu(II), Co(II), Ni(II), Cd(II) and Ru(III) ions with a tridentate NNO thiazole derived Schiff base', EKB Journal Management System, 34(part1), pp. 510-525. doi: 10.21608/jsrs.2018.14704
El-Medanib, S., Abdel Aaziza, A., Mohamed, R., Makhlouf, A., Mosad, S. Synthesis and characterization of Zn(II), Cu(II), Co(II), Ni(II), Cd(II) and Ru(III) ions with a tridentate NNO thiazole derived Schiff base. EKB Journal Management System, 2017; 34(part1): 510-525. doi: 10.21608/jsrs.2018.14704

Synthesis and characterization of Zn(II), Cu(II), Co(II), Ni(II), Cd(II) and Ru(III) ions with a tridentate NNO thiazole derived Schiff base

Journal of Scientific Research in Science
Article 35, Volume 34, part1, September 2017, Page 510-525  XML PDF (812.74 K)
Document Type: Original Article
DOI: 10.21608/jsrs.2018.14704
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Authors
Samir M. El-Medanib1; Ayman A. Abdel Aaziza2; Rania G. Mohamed1; Abdelmoneim A. Makhlouf1; Sherin A. Mosad* 3
1Chemistry Department, Faculty of Science, El-Fayoum University, 63514, El-Fayoum, Egypt.
2Chemistry Department, Faculty of Science, Ain Shams University, 11566, Abbassia, Cairo, Egypt.
3Chemistry Department, Faculty of Science, El-Fayoum University, 63514, El-Fayoum, Egypt
Abstract
Thermal reaction of Co(II), Ni(II), Cu(II), Zn(II), Cd(II) and Ru(III) metal ions with a tridentate Schiff-base ligand(HL) derived from the condensation of 2-aminothiazole and 2-hydroxy-1-naphthaldehyde resulted in the formation of a series of six new metal complexes: [Co(HL)2Cl2]; 1,[Ni(L)(CH3COO)(H2O)]; 2,[Cu(L)2]; 3, [Zn(L)2]; 4, [Cd(L)(CH3COO) (H2O)]H2O; 5, [Ru(L)2(H2O)2]Cl; 6. The ligand and its complexes were characterized by means of elemental and thermal analyses along with molar conductance and magnetic moment measurements as well as different spectroscopic techniques. The ESR spectrum of Cu(II) complex indicated elongated and covalent character of octahedral environment.
 
Keywords
Spectroscopic studies; Schiff base; Transition metal complexes, Thermal studies
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