Preparation and Characterization of some Polyalkylarylamines. | ||||
MEJ- Mansoura Engineering Journal | ||||
Article 18, Volume 13, Issue 2, December 1988, Page 27-37 PDF (569.87 K) | ||||
Document Type: Research Studies | ||||
DOI: 10.21608/bfemu.2021.173266 | ||||
View on SCiNiTO | ||||
Authors | ||||
A. Shaaban1; M. A. El-Komy2; A. A. Al-Sarwy2; I. Gar Al-Alam Rashed* 3 | ||||
1Department of Chemistry., Faculty of Science., Zagazig University (Benha Branch)., Benha., Egypt. | ||||
2Department of Physical and Mathematical Science., Faculty of Engineering (Shoubra)., Zagazig University., (Benno Branch., Cairo., Egypt. | ||||
3Associate Professor., Department of Physical Science., Faculty of Engineering., Mansoura University., El-Mansoura., Egypt. | ||||
Abstract | ||||
Adducts of polyalkylarylamines will stoichiometric amounts of stannous chloride were obtained by the reaction of 1,2-dichloroethane with m-phenylenediamine, p-phenylenediamine and 4,4 diaminodiphenyl in the presence of hydrochloric acid and stoichiometric amounts of stannous chloride in methanol as a solvent. Also, adduct of poly (chloromethyne-co- 4,4-dianiinodiphenyl) was obtained from the reaction of chloroform and benzidine by similar method. The structure of these adducts was confirmed by JR spectroscopy, as well 0.X-ray diffractometery, These adducts when reacted with aqueous solution of ammonium carbonate gave the corresponding polyalkylaryl-amine hydrochlorides. Also thermal analysis of these adducts were carried out . | ||||
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