Synthesis and Characterization of Novel Pellicular γ-Zirconium Phosphate-Phosphite/Fibrous Cerium Phosphate Nanocomposite Membranes
Shakshooki, S., Elakari, F., EL-Hamady, A., Elfituri, S., Elghariani, R. (2016). Synthesis and Characterization of Novel Pellicular γ-Zirconium Phosphate-Phosphite/Fibrous Cerium Phosphate Nanocomposite Membranes. EKB Journal Management System, 2(2), 1-5. doi: 10.12785/jpac/020104
S. K. Shakshooki; F. A. Elakari; A. M. EL-Hamady; S. M. Elfituri; R. Elghariani. "Synthesis and Characterization of Novel Pellicular γ-Zirconium Phosphate-Phosphite/Fibrous Cerium Phosphate Nanocomposite Membranes". EKB Journal Management System, 2, 2, 2016, 1-5. doi: 10.12785/jpac/020104
Shakshooki, S., Elakari, F., EL-Hamady, A., Elfituri, S., Elghariani, R. (2016). 'Synthesis and Characterization of Novel Pellicular γ-Zirconium Phosphate-Phosphite/Fibrous Cerium Phosphate Nanocomposite Membranes', EKB Journal Management System, 2(2), pp. 1-5. doi: 10.12785/jpac/020104
Shakshooki, S., Elakari, F., EL-Hamady, A., Elfituri, S., Elghariani, R. Synthesis and Characterization of Novel Pellicular γ-Zirconium Phosphate-Phosphite/Fibrous Cerium Phosphate Nanocomposite Membranes. EKB Journal Management System, 2016; 2(2): 1-5. doi: 10.12785/jpac/020104

Synthesis and Characterization of Novel Pellicular γ-Zirconium Phosphate-Phosphite/Fibrous Cerium Phosphate Nanocomposite Membranes

Journal of Pharmaceutical and Applied Chemistry
Volume 2, Issue 2, May 2016, Page 1-5  XML PDF (710.59 K)
Document Type: Original Article
DOI: 10.12785/jpac/020104
View on SCiNiTO View on SCiNiTO
Authors
S. K. Shakshooki1; F. A. Elakari1; A. M. EL-Hamady2; S. M. Elfituri3; R. Elghariani1
1Department of Chemistry, Faculty of Science, Tripoli University, P.O.Box 13203, Tripoli, Libya.
22Advanced laboratory for Chemical Analysis, Tripoli, Libya.
3Advanced laboratory for Chemical Analysis, Tripoli, Libya.
Abstract
Pellicular -zirconium phosphate-phosphite and nanofibrous cerium phosphate, -Zr.PO4.H2PO3.2H2O (p-ZrPP), Ce(HPO4)2.2.9H2O(nCePf ), respectively, were prepared and characterized by chemical, X-ray, thermal analysis and by FT- IR spectra. Composites of pellicuarl -zirconium phosphate-phosphite/nanofibrous cerium phosphate membranes were prepared by mixing slurry aqueous solutions of (p-ZrPP ) and (nCePf) at 450C for 48h, where the mixing ratios were 33:67 and 25:75 wt/wt%, p-ZrPP:nCePf, respectively. The resultant composite materials found to be:
[-Zr.PO4.H2PO3]0.34[Ce(HPO4)2]0.66.2.86H2O,and[-Zr.PO4.H2PO3]0.27[Ce(HPO4)2]0.73.2.17H2O, respectively. The composite membranes were homogeneous, flexible thin films with good mechanical texture. The resultant composites were
characterized by chemical, x-ray, thermal analysis and by FT- IR spectra. Tailor made of pellicular -Zirconium phosphate- phosphite /nanofibrous cerium phosphate composite membranes can be obtained , which mainly depend on wt/wt% mixing ratios of (p-ZrPP) /(nCePf) .These composites can be considered as new ion-exchangers , ionic conductors, and as solid acid catalysts.

Keywords
Pellicular γ-Zirconium Phosphate-Phosphite; Fibrous Cerium Phosphate; Nanocomposite Membranes
Statistics
Article View: 39
PDF Download: 46