Validation of k0-Standardization Procedure of Instrumental Neutron Activation Analysis at Ghana Research Reactor-1 Facility for the Determination of Rare Earth Elements
Asare, E., Klutse, C., Acquaye, F. (2022). Validation of k0-Standardization Procedure of Instrumental Neutron Activation Analysis at Ghana Research Reactor-1 Facility for the Determination of Rare Earth Elements. EKB Journal Management System, 55(2), 79-93. doi: 10.21608/ajnsa.2021.91014.1504
Ebenezer Aquisman Asare; Charles Kofi Klutse; Francis Yaw Acquaye. "Validation of k0-Standardization Procedure of Instrumental Neutron Activation Analysis at Ghana Research Reactor-1 Facility for the Determination of Rare Earth Elements". EKB Journal Management System, 55, 2, 2022, 79-93. doi: 10.21608/ajnsa.2021.91014.1504
Asare, E., Klutse, C., Acquaye, F. (2022). 'Validation of k0-Standardization Procedure of Instrumental Neutron Activation Analysis at Ghana Research Reactor-1 Facility for the Determination of Rare Earth Elements', EKB Journal Management System, 55(2), pp. 79-93. doi: 10.21608/ajnsa.2021.91014.1504
Asare, E., Klutse, C., Acquaye, F. Validation of k0-Standardization Procedure of Instrumental Neutron Activation Analysis at Ghana Research Reactor-1 Facility for the Determination of Rare Earth Elements. EKB Journal Management System, 2022; 55(2): 79-93. doi: 10.21608/ajnsa.2021.91014.1504

Validation of k0-Standardization Procedure of Instrumental Neutron Activation Analysis at Ghana Research Reactor-1 Facility for the Determination of Rare Earth Elements

Arab Journal of Nuclear Sciences and Applications
Article 9, Volume 55, Issue 2, April 2022, Page 79-93  XML PDF (681.22 K)
Document Type: Original Article
DOI: 10.21608/ajnsa.2021.91014.1504
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Authors
Ebenezer Aquisman Asare email 1; Charles Kofi Klutse2; Francis Yaw Acquaye3
1Universiti Malaysia Sarawak
2Nuclear Power Institute, Ghana Atomic Energy Commission (GAEC), Atomic-Ghana
3Department of Chemistry and Biochemistry, College of Arts and Sciences, University of Alabama, Alabama, U.S.A
Abstract
The current approach for accurate determination for rare earth elements using environmental reference materials for k0-INAA with short turnaround analysis times was investigated. The k0 and Q0 values for REEs, nuclear interference, and spectral interference were practically assessed and improved with the standard reference material. The evaluation of the current iterative neutron self-shielding and gamma-ray self-attenuation was established using reference material prepared from 100 mg/kg of 99.9% certified reference material (i.e., Alfa Aesar mono rare earth oxide combined with SiO2). The general achievement of the current k0-INAA technique for rare earth elements was validated with IAEA Soil-7 reference material and real sediment samples. The rare earth elements levels in the reference material range from 0.72 ± 0.08 mg/kg for 166Ho to 60.8 ± 2.1 mg/kg for 141Ce. The uncertainty at which the rare earth element concentration was examined is below 8% (at 95% confidence level). This showed good uniformity with the IAEA Soil-7 certified contents. In addition, k0-NAA is able to quantify most of the REEs in real samples collected from three locations in Ghana.
Keywords
Rare-earth element; Environmental reference material; k0-standardization technique; Gamma-ray spectrometer
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