Study of voltammetry behavior of complexation for nano-copper sulfate (NCSu) with cefdinir antibiotic (CFD) using glassy carbon electrode (GCE) in mixed 5% v/v (DMF-H2O) solvents | ||||
| Assiut University Journal of Multidisciplinary Scientific Research | ||||
| Volume 47, Issue 1, June 2018, Page 38-50 PDF (1.02 MB) | ||||
| Document Type: Novel Research Articles | ||||
| DOI: 10.21608/aunj.2018.221342 | ||||
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| Abstract | ||||
| Cyclic voltammetry of nano-copper (II) complex (NCSu) with Cefdinir antibiotic (CFD) was studied using a glassy carbon electrode (GCE) in 0.1M KCl as a supporting electrolyte in 5% (v/v) mixed (DMF-H2O) solvent at two temperatures (298.15, 303.15 K). It was observed that copper (II) (NCSu) in nano form and Cefdinir antibiotic (CFD) form 1:1 and 1:2 ratio complexes. The complexation stability constants and Gibbs free energies of solvation were evaluated. Also the different thermodynamic parameters, enthalpies and entropies of complex formation were estimated. . The scan rate of nano-copper (II) (NCSu) in the absence and presence of cefdinir antibiotic (CFD) were studied. All mechanisms of electrode reactions were discussed and comparing the biological activities of bulk and nano- Cefdinir copper (II) complexes. | ||||
| Keywords | ||||
| Cyclic voltammetry; thermodynamics; Cefdinir antibiotic; stability constant | ||||
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