Water Soluble CdO-PANI Composite as Corrosion Resistive Delegate in Acidic Abode for Mild Steel
Shunmugaperumal, S., Selvaraj P, K., Sivalingam, S. (2022). Water Soluble CdO-PANI Composite as Corrosion Resistive Delegate in Acidic Abode for Mild Steel. EKB Journal Management System, 65(131), 291-299. doi: 10.21608/ejchem.2022.118204.5336
Selvaraj Shunmugaperumal; Kamatchi Selvaraj P; Sivakumar Sivalingam. "Water Soluble CdO-PANI Composite as Corrosion Resistive Delegate in Acidic Abode for Mild Steel". EKB Journal Management System, 65, 131, 2022, 291-299. doi: 10.21608/ejchem.2022.118204.5336
Shunmugaperumal, S., Selvaraj P, K., Sivalingam, S. (2022). 'Water Soluble CdO-PANI Composite as Corrosion Resistive Delegate in Acidic Abode for Mild Steel', EKB Journal Management System, 65(131), pp. 291-299. doi: 10.21608/ejchem.2022.118204.5336
Shunmugaperumal, S., Selvaraj P, K., Sivalingam, S. Water Soluble CdO-PANI Composite as Corrosion Resistive Delegate in Acidic Abode for Mild Steel. EKB Journal Management System, 2022; 65(131): 291-299. doi: 10.21608/ejchem.2022.118204.5336

Water Soluble CdO-PANI Composite as Corrosion Resistive Delegate in Acidic Abode for Mild Steel

Egyptian Journal of Chemistry
Volume 65, Issue 131, December 2022, Page 291-299  XML PDF (637.78 K)
Document Type: Original Article
DOI: 10.21608/ejchem.2022.118204.5336
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Authors
Selvaraj Shunmugaperumal email orcid 1; Kamatchi Selvaraj Porcid 2; Sivakumar Sivalingamorcid 3
1University of Madras
2PG & Research Department of Chemistry Government Arts College for Men (Autonomous) Nandanam, Chennai-600 035. INDIA (Affiliated to University of Madras)
3Vel Tech Rangarajan Dr.Sagunthala R&D Institute of Science and Technology, Avadi,Chennai-62, Tamil Nadu, India.
Abstract
Deployment of ammonium peroxydisulphate as oxidant and sodium salt of dodecylbenzene sulphonic acid as dopant as well as surfactant at ±5 ºC causes oxidative polymerization of aniline. Inclusion of CdO nanoparticles during oxidative polymerization yielded water soluble CdO-PANI composite. Formation of composite material was confirmed by comparing the results obtained in the FTIR, XRD and SEM spectral analysis with the reported values. Weight loss measurements by gravimetric method reveal the resisting adeptness of composite, 89% even after eight hours, against acidic environment. Open circuit potential measurement for 120 minutes exposes that raise in the concentration of composite shift the potential value to positive side. Potentiodynamic polarization and electrochemical impedance spectroscopy measurements also discloses the impervious nature of the synthesized material. Impregnable working environment can be provided by the prepared composite during industrial maintenance process.
Keywords
CdO-PANI; Mild steel; OCP; Potentiodynamic polarization; EIS, Poly composite
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