Removal of Lead and Cadmium ions from Wastewater by Using Eco-friendly Nanocomposite | ||||
Advances in Environmental and Life Sciences | ||||
Article 3, Volume 2, Issue 2, November 2022, Page 1-12 PDF (2.61 MB) | ||||
Document Type: Original research articles | ||||
DOI: 10.21608/aels.2022.144230.1017 | ||||
View on SCiNiTO | ||||
Authors | ||||
Rasha Atef Shoman 1; Sayed Ahmed Eltohamy1; Adel Sayed Orabi2; Abbas Mamdoh Abbas2 | ||||
1Environmental Research Department, Land, Water and Environment Institute, Agricultural Research Center(ARC), Ministry of Agriculture and Land Reclamation, 9-Cairo university street, Giza, 12112, Egypt. | ||||
2Chemistry Department, Faculty of Science, Suez Canal University. Ismailia, 41522, Egypt. | ||||
Abstract | ||||
Eco-friendly nanocomposite (HS) was prepared from agriculture sources and characterized for remediation of wastewater from lead and cadmium ions. The nanocomposite was prepared from humic acid with silica (HS) which was prepared from compost and rice husk. The nanocomposite was characterized by FTIR, XRD, SEM, Zeta potential, BET and SEM-EDX. The removal of metal ions was studied using a variety of operating parameters, including pH, metal ion concentration, adsorbent dosage, and contact time. In both Pb2+ and Cd2+, the best removal efficiency was found at pH 5.6 and 6. Pb2+ and Cd2+ had equilibrium times of 30 and 60 minutes, respectively. The adsorption process was exothermic and spontaneous in nature, according to thermodynamics. In terms of describing and evaluating the adsorption process, the Langmuir, Freundlich, and Temkin models are the most accurate, according to isotherm adsorption studies. Nanocomposite (HS) before and after adsorption was confirmed by EDX to involve lead and cadmium ions. The adsorption capacity of HS was 22.86 and 6.25 mg/g for Pb2+ and Cd2+, respectively. | ||||
Keywords | ||||
Humic acid; Silica; Nanocomposite; Lead; Cadmium | ||||
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