Iron-Trimesic Metal Organic Frameworks as Nano-Adsorbents for Tetracycline and Ceftriaxone Contaminated Wastewater Effluents
Nassar, H., Shaban, A., zaher, A., Abdelmonein, T., Salama, E., gaber, Y., Shehata, N., Abdelhameed, R., Mahmoud, R. (2023). Iron-Trimesic Metal Organic Frameworks as Nano-Adsorbents for Tetracycline and Ceftriaxone Contaminated Wastewater Effluents. EKB Journal Management System, 66(7), 439-449. doi: 10.21608/ejchem.2022.153568.6647
Hossam F. Nassar; Alzahraa Shaban; amal zaher; Taha Abdelmonein; Esaraa Salama; yasser gaber; Nabila Shehata; Reda Abdelhameed; Rehab Mahmoud. "Iron-Trimesic Metal Organic Frameworks as Nano-Adsorbents for Tetracycline and Ceftriaxone Contaminated Wastewater Effluents". EKB Journal Management System, 66, 7, 2023, 439-449. doi: 10.21608/ejchem.2022.153568.6647
Nassar, H., Shaban, A., zaher, A., Abdelmonein, T., Salama, E., gaber, Y., Shehata, N., Abdelhameed, R., Mahmoud, R. (2023). 'Iron-Trimesic Metal Organic Frameworks as Nano-Adsorbents for Tetracycline and Ceftriaxone Contaminated Wastewater Effluents', EKB Journal Management System, 66(7), pp. 439-449. doi: 10.21608/ejchem.2022.153568.6647
Nassar, H., Shaban, A., zaher, A., Abdelmonein, T., Salama, E., gaber, Y., Shehata, N., Abdelhameed, R., Mahmoud, R. Iron-Trimesic Metal Organic Frameworks as Nano-Adsorbents for Tetracycline and Ceftriaxone Contaminated Wastewater Effluents. EKB Journal Management System, 2023; 66(7): 439-449. doi: 10.21608/ejchem.2022.153568.6647

Iron-Trimesic Metal Organic Frameworks as Nano-Adsorbents for Tetracycline and Ceftriaxone Contaminated Wastewater Effluents

Egyptian Journal of Chemistry
Volume 66, Issue 7, July 2023, Page 439-449  XML PDF (1.88 MB)
Document Type: Original Article
DOI: 10.21608/ejchem.2022.153568.6647
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Authors
Hossam F. Nassarorcid 1; Alzahraa Shaban2; amal zaherorcid 3; Taha Abdelmonein2; Esaraa Salama4; yasser gaber5; Nabila Shehata6; Reda Abdelhameed7; Rehab Mahmoud email 2
1Department of Environmental Sciences and Industrial Development, Faculty of Post Graduate Studies for Advanced Sciences, Beni-Suef university
2Chemistry Department. Faculty of Sciences. Beni-Suef University. Beni-Suef Egypt.
3Environmental Sciences and Industrial Development Department. Faculty of Postgraduate Studies for Advanced Sciences. Beni-Suef University. Beni-Suef Egypt. Egypt eni-Suef university
4Biotechnology Department. Faculty of Postgraduate Studies for Advanced Sciences. Beni-Suef University. Beni-Suef Egypt.
5Department of Materials Science and Nanotechnology, Faculty of Postgraduate Studies for Advanced Sciences, Beni-Suef University, Beni-Suef 62511, Egypt
6ESID dep, PSAS Faaculty, Beni-Suef University, 62511 Beni-Suef, Egypt
7Applied Organic Chemistry Department, National Research Centre, 33 EL Bohouth st., Dokki, Giza, Egypt.
Abstract
Antibiotics release has been identified as a series concern with adverse effects on the ecosystem. Nano-adsorbents are promising materials to remove antibiotics from wastewater effluents. In this work, iron-trimesic metal organic frameworks (Fe-BTC MOF) was synthesized and characterized by XRD, FTIR, SEM and TEM. Fe-BTC was then investigated as nano-adsorbent for tetracycline (TC) and Ceftriaxone sodium (CFTR) antibiotics. TC and CFTR are common antibiotics, which are extensively used by industrial activities and thereby are released to wastewater effluents. Fe-BTC MOF showed high adsorption capacity of 713 and 1284.6 mg/g for TC and CFTR respectively. This study aim to compares the uptake efficiencies for two drug residues. Single antibiotic residues adsorption tests showed that Fe-BTC MOF effectively takes up TC more than CFTR. The influence of pH, dose, concentration and time on the adsorption process was estimated. Such adsorption capacity of Fe-BTC will make it favorable for further environmental applications.
Keywords
Fe-BTC MOF; wastewater; adsorption; Tetracycline; Ceftriaxone sodium
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