Surfactant assisted spectrophotometric determination of copper(II), and mercury(II) in real samples using 2- amino-4-((4- nitrophenyl)diazenyl)pyridine-3-ol
Moustafa, A., El-Sayed, H., Amin, A., El-Haggar, A., Gouda, A. (2023). Surfactant assisted spectrophotometric determination of copper(II), and mercury(II) in real samples using 2- amino-4-((4- nitrophenyl)diazenyl)pyridine-3-ol. EKB Journal Management System, 2023(3), 11-26. doi: 10.21608/bfszu.2022.178725.1219
Ahmed H. Moustafa; Hassan A El-Sayed; Alaa S Amin; Asmaa El-Haggar; Ayman A Gouda. "Surfactant assisted spectrophotometric determination of copper(II), and mercury(II) in real samples using 2- amino-4-((4- nitrophenyl)diazenyl)pyridine-3-ol". EKB Journal Management System, 2023, 3, 2023, 11-26. doi: 10.21608/bfszu.2022.178725.1219
Moustafa, A., El-Sayed, H., Amin, A., El-Haggar, A., Gouda, A. (2023). 'Surfactant assisted spectrophotometric determination of copper(II), and mercury(II) in real samples using 2- amino-4-((4- nitrophenyl)diazenyl)pyridine-3-ol', EKB Journal Management System, 2023(3), pp. 11-26. doi: 10.21608/bfszu.2022.178725.1219
Moustafa, A., El-Sayed, H., Amin, A., El-Haggar, A., Gouda, A. Surfactant assisted spectrophotometric determination of copper(II), and mercury(II) in real samples using 2- amino-4-((4- nitrophenyl)diazenyl)pyridine-3-ol. EKB Journal Management System, 2023; 2023(3): 11-26. doi: 10.21608/bfszu.2022.178725.1219

Surfactant assisted spectrophotometric determination of copper(II), and mercury(II) in real samples using 2- amino-4-((4- nitrophenyl)diazenyl)pyridine-3-ol

Bulletin of Faculty of Science, Zagazig University
Article 2, Volume 2023, Issue 3, October 2023, Page 11-26  XML PDF (1.06 MB)
Document Type: Original Article
DOI: 10.21608/bfszu.2022.178725.1219
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Authors
Ahmed H. Moustafa1; Hassan A El-Sayed2; Alaa S Amin3; Asmaa El-Haggar4; Ayman A Gouda email 5
1Department of Chemistry, Faculty of Science, Zagazig University, Zagazig, Egypt.
2Department of Chemistry, Faculty of Science, Zagazig University,
3Chemistry Department, Faculty of Sciences, Benha University, Benha, Egypt.
4Chemistry Department, Faculty of Sciences, Zagazig University, Zagazig, 44519, Egypt.
5Chemistry Department, Faculty of Science, Zagazig University, Zagazig, Egypt
Abstract
Using 2-amino-4-(4-nitrophenyl) diazenyl) pyridine-3-ol (ANPDP) as a reagent, a sensitive and selective surfactant-assisted spectrophotometric method for the rapid determination of copper (II) and mercury (II) was proposed. When the ANPDP reagent reacts with both Cu(II) and Hg(II) ions in a universal buffer solution containing sodium dodecyl sulfate, it produces a violet color. Cu(II) and Hg(II) had the highest absorbance at 565 and 605 nm, respectively. The complexes of Cu(II) and Hg(II) have a mole ratio of 1:2 [M:L]. Cu(II) and Hg(II) have linear ranges of 10-180 and 10-160 g mL1, respectively, with detection limits of 1.36 and 1.74 g mL1 and quantification limits of 4.1 and 5.26 g mL1. The complex's correlation coefficients of 0.994 and 0.995, respectively, show high linearity. Cu(II) and Hg(II) relative standard deviations for six replication measurements were 1.01% and 1.2%, respectively. The analytical parameters for the procedure were optimized. Most other metals and rather high concentrations of co-existing elements can be tolerated. This method has the benefits of being quick, easy, sensitive, and selective, and it was successfully used to determine the presence of Cu(II) and Hg(II) ions in real samples, and recovery percentage was found to be 95.0-98.0 %.
Keywords
Copper; Mercury; ANPDP; Surfactant assisted spectrophotometry; Environmental samples
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