Thermal treatment of lead-rich dust to improve fresh characteristics and adsorption behavior of autoclaved geopolymer for methylene blue dye removal | ||||
| Egyptian Journal of Chemistry | ||||
| Volume 66, Issue 13, December 2023, Page 1633-1644 PDF (1.37 MB) | ||||
| Document Type: Original Article | ||||
| DOI: 10.21608/ejchem.2023.227260.8367 | ||||
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| Authors | ||||
Ali M. Abdel-Aziz   1; M. Ramadan2; Alaa Mohsen 3; Mostafa A. Sayed2
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| 1Chemistry department, Faculty of Science, Ain Shams University | ||||
| 2Chemistry Department, Faculty of Science, Ain Shams University | ||||
| 3Faculty of Engineering, Ain Shams University | ||||
| Abstract | ||||
| The main target behind this work is studying the synergistic returns of thermal treatment of Lead-rich sludge dust (LD) on fresh properties of alkali-activated geopolymer in addition to its adsorption performance towards the removal of methylene dye (MB) from aqueous media. According to TGA/DTGA analysis, the thermal treatment of received dust was at 500°C (TLD). Two geopolymeric pastes (Geo-LD and Geo-TLD) were prepared using NaOH solution. The binders of the first paste were composed of 50%slag +50%LD while the binders of the second paste were composed of 50%slag + 50%TLD; respectively. Regarding fresh properties, it was found that the initial/final-setting time (I/F-ST) of Geo-LD is longer than Geo-TLD by 472 and 535 min, respectively. Moreover, a significant increment in the spread area is observed from 38 cm2 as in case of Geo-LD to 216 cm2 for Geo-TLD. After alkali-hydrothermal activation, the measured compressive strength values at 5bars/4h for Geo-LD and Geo-TLD were 43 and 72 MPa; respectively. FTIR, X-ray diffraction (XRD), and Scanning electron microscopy (SEM) techniques confirmed that Geo-TLD activated powder contained zeolitic phases, calcium-silicate-hydrate (C-S-H), calcium-alumino-silicate-hydrate (C-A-S-H), and lead silicates. N2-adsorption/desorption studies affirmed the high adsorption capacity of Geo-TLD activated powder. The generated product (Geo-TLD) was found to have a maximum MB adsorption capacity of 210 mg/g at the optimized conditions. The Langmuir isotherm model (R2 = 0.9849) offers the best match and is the most appropriate for the experimental data. According to our results, MB adsorption on Geo-TLD takes place as monolayer adsorption on a surface with homogenous adsorption affinity. Moreover, the adsorption kinetics was better explained by the pseudo-second-order kinetic model. | ||||
| Keywords | ||||
| Geopolymer; Lead-rich sludge dust; Thermal treatment; Adsorption; Methylene blue; Compressive strength | ||||
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