EFFECT OF TRANSITION METAL INCORPORATION IN MCM-41 ON THE PHOTOCATALYTIC DEGRADATION OF CHLOROPHENOL. PART I CHROMIUM | ||||
The International Conference on Chemical and Environmental Engineering | ||||
Article 15, Volume 3, 3rd International Conference On Chemical & Environmental Engineering, May 2006, Page 195-211 PDF (418.87 K) | ||||
Document Type: Original Article | ||||
DOI: 10.21608/iccee.2006.41067 | ||||
View on SCiNiTO | ||||
Authors | ||||
Aboul-Gheit A. K.1; Emara M. M.2; Ali R. A.2; El-Moselhy M. M.2 | ||||
1Egyptian Petroleum Research Institute, Cairo, Egypt. | ||||
2Faculty of science, Alazhar university. | ||||
Abstract | ||||
ABSTRACT MCM-41 modification with Cr cation was carried out by direct synthesis using of the surfactant templating process and the impregnation method. The produced molecular sieves were characterized by XRD, FTIR spectroscopy and N2 adsorption-desorption. All prepared materials acquired a typical MCM-41 structure. The prepared samples were tested in the photocatalytic degradation of 3-chlorophenol in aqueous medium. The reactants and products were analyzed using high performance liquid chromatography (HPLC) and ion chromatography (IC). The data obtained indicate that the structure modifications of MCM-41 affected not only the activity of MCM-41 for the disappearance of chlorophenol but also for the degradation intermediates. | ||||
Keywords | ||||
Mesoporous; catalyst synthesis; MCM-41 Photolysis; 3-Chlorophenol; UV irradiation; HPLC; IC | ||||
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