Effect of Gamma Irradiation on High Lead Borate Glass Doped with Tungsten Oxide | ||||
| Egyptian Journal of Chemistry | ||||
| Article 24, Volume 63, Issue 6, June 2020, Page 2319-2330 PDF (1.88 MB) | ||||
| Document Type: Original Article | ||||
| DOI: 10.21608/ejchem.2019.18810.2158 | ||||
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| Authors | ||||
E. Nabhan1; M.A. El-Ahdal2; W. H. El-Abbady1; S. S. Elosily  2
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| 1Physics Department, Faculty of Science, (Girls branch), Al-Azhar University, Egypt | ||||
| 2national center for radiation researches and technology | ||||
| Abstract | ||||
| X-ray, Ultraviolet and Fourier Transform infrared spectral properties of tungsten ions doped in a host lead borate glass have a composition [60%PbO and 40%B2O3 weight%] was studied. Effect of gamma irradiation on the prepared glass samples was surveyed. Amorphization of the studied glass samples have been checked by X ray. Deep inspection for density, molar volume, UV and FTIR for base glass and tungsten oxide with different concentrations (0.15-2.28) weight% proved that the tungsten ions are pronounced as structural groups mostly in the hexavalent W6+. The constancy of optical absorption spectral curves reversed the shielding behavior for this combined glass towards successive gamma irradiation. Glasses containing high lead oxide content are extensively used for multi-applications including lead crystal glass and some special optical glasses, low-melting solder glasses and radiation protection windows and even in immobilization of radioactive nuclear wastes. | ||||
| Keywords | ||||
| Keywords: Lead borate glass; Density and molar volume; FT-IR spectroscopy; Gamma Irradiation; Optical characteristics; Gamma attenuation | ||||
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