THERMAL STABILITY OF Ni(II) AND Cu(II) MIXED LIGAND COMPLEXES DERIVED FROM BIOLOGICALLY IMPORTANT SCHIFF BASES, AZOLES AND MORPHOLINE | ||||
Bulletin of Pharmaceutical Sciences Assiut University | ||||
Article 6, Volume 31, Issue 1, June 2008, Page 93-108 PDF (262.56 K) | ||||
Document Type: Original Article | ||||
DOI: 10.21608/bfsa.2008.64218 | ||||
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Authors | ||||
Aref A. M. Aly1; Ahmed H. Osman1; Mohamed Abd El-Mottaleb2; Gamal A. H. Gouda2 | ||||
1Department of Chemistry, Faculty of Science, Assiut University, Assiut, Egypt | ||||
2Department of Chemistry, Faculty of Science, Al-Azhar University, Assiut, Egypt | ||||
Abstract | ||||
Thermogravimetry (TG) and differential thermogravimetry (DTG) have been applied to the investigation of the thermal behavior of six mixed ligand complexes of Ni(II) and Cu(II) comprising the Schiff bases: o-hydroxyacetophenoneethanolimine (OHAE), N-salicylidene-o-iminophenol (SOP) and N-salicylideneo- toluidine (SOT) as well as morpholine (Morph) and certain azoles. The azoles used are: 2-amino-thiazole (2-Atz), benzothiazole (Btz), 2-methylbenzothiazole (2-Mbtz), 3-methyl-2- selenoxobenzothiazole (3-Msbtz) and thiabendazole (Tbdz). Heating the compounds first results in a release of the morpholine or the azoles. Kinetics of the decomposition reactions were studied using non-mechanistic equations. | ||||
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