Modification of Chitosan as Chemical Admixture for Cement Pastes
Bekbayeva, L., Negim, E., Yeligbayeva, G., Ganjian, E. (2020). Modification of Chitosan as Chemical Admixture for Cement Pastes. EKB Journal Management System, 63(4), 1497-1508. doi: 10.21608/ejchem.2019.18136.2107
Lyazzat Bekbayeva; El-Sayed Moussa Negim; G Yeligbayeva; Eshmaiel Ganjian. "Modification of Chitosan as Chemical Admixture for Cement Pastes". EKB Journal Management System, 63, 4, 2020, 1497-1508. doi: 10.21608/ejchem.2019.18136.2107
Bekbayeva, L., Negim, E., Yeligbayeva, G., Ganjian, E. (2020). 'Modification of Chitosan as Chemical Admixture for Cement Pastes', EKB Journal Management System, 63(4), pp. 1497-1508. doi: 10.21608/ejchem.2019.18136.2107
Bekbayeva, L., Negim, E., Yeligbayeva, G., Ganjian, E. Modification of Chitosan as Chemical Admixture for Cement Pastes. EKB Journal Management System, 2020; 63(4): 1497-1508. doi: 10.21608/ejchem.2019.18136.2107

Modification of Chitosan as Chemical Admixture for Cement Pastes

Egyptian Journal of Chemistry
Article 24, Volume 63, Issue 4, April 2020, Page 1497-1508  XML PDF (1.31 MB)
Document Type: Original Article
DOI: 10.21608/ejchem.2019.18136.2107
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Authors
Lyazzat Bekbayevaorcid 1; El-Sayed Moussa Negim email orcid 2; G Yeligbayeva3; Eshmaiel Ganjianorcid 4
1Institute of Chemical and Biological Technologies, Satbayev University, 22 Satpayev Street, 050013 Almaty, Kazakhstan
2School of Chemical Engineering, Kazakh-British Technical University, Almaty, Kazakhstan
3School of Chemical and Biological Technologies, Satbayev University, 22 Satpayev Street, 050013 Almaty, Kazakhstan
4School of Energy, Construction and Environment, Faculty of Engineering, Environment & Computing, Sir John Laing Building, JL138, Coventry University, Coventry, CV1 2HF
Abstract
Three different composition ratios of chitosan-g- acrylic acid, P[Ch-g-AA] were prepared in the presence of potassium persulphate as an initiator using free radical technique. The grafted copolymers were characterized through FT-IR, TGA, DSC, and SEM. The results showed that these grafted copolymers have a single glass transition indicating that these copolymers can form a miscible phase. The P[Ch-g-AA] exhibit thermal stability. SEM of the grafted copolymers showed no phase separation, when compared with the pure Ch. The effect of grafted copolymers on the physico-mechanical properties of cement pastes was investigated. The addition of water mixed with grafted copolymer to the cement, improves properties of cement pastes. As the ratios of AA in the grafted copolymer increases, the water-to-cement (WC) ratio, setting time as well as water absorption decreases. While The compressive strength was sharply increased at nearly all hydration ages.
Keywords
Chitosan; Acrylic Acid; Grafting polymerization; Portland Cement
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