Metal complexes of new pyrimidine azodye ligands synthesis, spectral studies, thermal analysis, X-ray diffraction and uses in ink synthesis. | ||||
Al-Azhar Bulletin of Science | ||||
Article 1, Volume 22, Issue 2-A, December 2011, Page 1-16 PDF (299.08 K) | ||||
Document Type: Original Article | ||||
DOI: 10.21608/absb.2011.7012 | ||||
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Authors | ||||
Ali M. HASSAN* 1; A. M. NASSAR1; Y. ABO ZAID2; N. ABD EL-RAHMAN2; M. ABO ALI2; T. M. KEHELA1 | ||||
1Chemistry Department, Faculty of Science Al-Azhar University, Cairo, Egypt. | ||||
2Chemistry Department, Faculty of Science Al-Azhar University, Cairo, Egypt | ||||
Abstract | ||||
Novel azodye ligands 2-Amino-3- (4-chloro phenylazo )-7-(4-fluorophenyl)-5-(thiophen-2-yl)-6,7-dihydropyrazolo (1,5-a) pyrimidine ( L1 ) and 2-Amino-3- (4-chlorophenylazo )-5,7-Di(thiophen-2-yl)-6,7-dihydropyrazolo(1,5-a) pyrimidine ( L2 ) and their complexes with Fe (III) , Co (II), Ni (II) and Cu (II) have been synthesized. The stereochemistry and the mode of bonding of the complexes were achieved based on elemental analysis , IR, UV-Vis, 1HNMR, MS and ESR spectroscopy as well as (TGA). Octahedral structure proposed for geometry of the chelates based on their electronic spectra and magnetic susceptibility. The metal complexes show no bleeding and tinting strength properties for ink synthesis. | ||||
Keywords | ||||
Metal complexes; pyrimidine azodye ligands; ink synthesis | ||||
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