SYNTHESIS AND CHARACTERIZATION OF A NONIONIC SURFACTANT AS A CORROSION INHIBITOR FOR STEEL IN 1.0 M HCL. | ||||
| Al-Azhar Bulletin of Science | ||||
| Article 4, Volume 23, Issue 2-A, December 2012, Page 77-96 PDF (1.32 MB) | ||||
| Document Type: Original Article | ||||
| DOI: 10.21608/absb.2012.7205 | ||||
 View on SCiNiTO | ||||
| Authors | ||||
| S. A. SOLIMAN; M. S. METWALLY; S. R. SELIM; M. A. BEDAIR* | ||||
| Chemistry Department, Faculty of Science, Al -Azhar University, Cairo, Egypt. | ||||
| Abstract | ||||
| Synthesis, adsorption and corrosion inhibiting effect of new nonionic surfactant consisting of 3-[(4-Dimethylamino-benzylidene)-amino]-4-hydroxy-benzenesulphonic acid as hydrophobic part and poly ethylene glylcol (poly ethylene oxide) on steel in 1.0 M HCl was investigated using weight loss and potentiodynamic polarization techniques. The experimental findings revealed that this compound inhibited the corrosion reaction in 1.0 M HCl environment. The results indicated that this surfactant was adsorbed on the metal/solution interface. A theoretical study of the adsorption behavior of this compound was carried out in the framework of the semiempirical (SE) and molecular dynamics (MD). | ||||
| Keywords | ||||
| weight loss; Potentiodynamic polarization; Adsorption isotherm; Nonionic surfactant; Quantum chemical studies | ||||
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