KINETICS OF ESTERIFICATION OF OLEIC AND LINOLEIC FREE FATTY ACIDS
A. Hawash, S., Esmail Ebrahiem, E., A. Farag, H. (2020). KINETICS OF ESTERIFICATION OF OLEIC AND LINOLEIC FREE FATTY ACIDS. EKB Journal Management System, 39(1), 25-36. doi: 10.21608/jaet.2020.73328
Samah A. Hawash; Ebrahiem Esmail Ebrahiem; Hassan A. Farag. "KINETICS OF ESTERIFICATION OF OLEIC AND LINOLEIC FREE FATTY ACIDS". EKB Journal Management System, 39, 1, 2020, 25-36. doi: 10.21608/jaet.2020.73328
A. Hawash, S., Esmail Ebrahiem, E., A. Farag, H. (2020). 'KINETICS OF ESTERIFICATION OF OLEIC AND LINOLEIC FREE FATTY ACIDS', EKB Journal Management System, 39(1), pp. 25-36. doi: 10.21608/jaet.2020.73328
A. Hawash, S., Esmail Ebrahiem, E., A. Farag, H. KINETICS OF ESTERIFICATION OF OLEIC AND LINOLEIC FREE FATTY ACIDS. EKB Journal Management System, 2020; 39(1): 25-36. doi: 10.21608/jaet.2020.73328

KINETICS OF ESTERIFICATION OF OLEIC AND LINOLEIC FREE FATTY ACIDS

Journal of Advanced Engineering Trends
Article 3, Volume 39, Issue 1, January 2020, Page 25-36  XML PDF (1.14 MB)
DOI: 10.21608/jaet.2020.73328
View on SCiNiTO View on SCiNiTO
Authors
Samah A. Hawash email 1; Ebrahiem Esmail Ebrahiem2; Hassan A. Farag3
1Assistant Lecturer in Petrochemical Department, Faculty of Engineering, Pharos University
2Professor in Chemical Engineering Department, Faculty of Engineering, Minia University
3Professor in Chemical Engineering Department, Faculty of Engineering, Alexandria University
Abstract
        The kinetics of the esterification of oleic and linoleic acids using a batch reactor are described                                     in this study. Effect of relevant factors on ester conversion, such as reaction temperature, dose of sulphuric acid as a catalyst, and methanol/FFAs (oleic and linoleic acid) mole ratios are studied. The results showed that the maximum conversion of oleic and linoleic were 88% at 40:1 methanol/FFA molar ratio at 68°C, catalyst 2 wt. % of FFA and reaction time 30 min. A pseudo-homogeneous kinetic model was proposed for the esterification. The influence of Temperature on the rate constants is presented by Arrhenius equation, and the activation energies were found to be 43.42 and 45.51 kJ/mol for linoleic and oleic acid, respectively. 
Keywords
Esterification; Oleic acid; Linoleic acid; Methanol; Kinetics
References
  1. Ding, J.; He, B.; Li, J. Biodiesel Production From Acidified Oils Via Supercritical Methanol, Energies, 4:2212–23, 2011.
  2. Ramadhas, A. S.; Jayaraj, S.; Muraleedharan, C. Biodiesel Production From High FFA Rubber Seed Oil, Fuel , 84:335–40, 2015.
  3. Donato, A. G. Aranda; Rafael, T. P. Santos; Neyda, C. O. Tapanes; Andre´ Luis Dantas Ramos; Octavio Auqusto, C. Antunes Acid-Catalyzed Homogeneous Esterification Reaction For Biodiesel Production From Palm Fatty Acids, Springer Science and Business Media, 122:20–25, 2018.
  4. Ackman, R. G., Kates, M. and Hansen, R. P., Biochim. Biophys. Acta, 176, 673-674, 1969.
  5. Christie, W.W. Preparation Of Ester Derivatives Of Fatty Acids For Chromatographic Analysis, Advances in Lipid Methodology – Two, pp. 69-111, 1993.
  6. Thiruvengadaravi, K. V.; Nandagopal, J.; Bala, V. S. S.; Kirupha, S. D.;Vijayalakshmi, P.; &Sivanesan, S. Kinetic Study Of The Esterification Of Free Fatty Acids In Non-Edible PongamiaPinnata Oil Using Acid Catalyst, Indian Journal of Science and Technology, 2(12), 2009.
  7. Cardoso, A. L.; Neves, S. C. G.; & Da Silva, M. J. Esterification of Oleic Acid for Biodiesel Production Catalyzed by SnCl2: A Kinetic Investigation, Energies, 1(2): 79-92, 2008.
  8. Yadav, P. K.; Singh, O.; & Singh, R. P. Palm Fatty Acid Biodiesel:Process Optimization and Study of Reaction Kinetics, Journal of Oleo Science, 59(11): 575-580, 2010.
  9. Berrios, M.; Siles, J.; Martin, M. A.; & Martin, A. A Kinetic Study Of The Esterification Of Free Fatty Acids (FFA) In Sunflower Oil, Fuel, 86(15): 2383-2388, 2007.
  10. Sendzikiene, E.; Makareviciene, V.; Janulis, P.; &Kitrys, S. Kinetics of Free Fatty Acids Esterification With Methanol in The Production Of Biodiesel Fuel, European journal of lipid science and technology, 106(12): 831-836, 2004.
  11. Agra, I.B.; Warnijati, S.; Wiratni, B. Two Steps Ethanolysis Of Castor Oil Using Sulphuric Acid As Catalyst To Produce Motor Oil, Werc., 9:1025–1028, 1996.
  12. Goyal, P.; Sharma, M.P.; Jain, S. Optimization of Esterification and Transesterification of High FFA Jatropha Curcas Oil Using Response Surface Methodology, Journal of Petroleum Science Research, Volume 1, pp. 36-43, 2018.
  13. Rofiqah, U.;Djalal, R.A.; Sutrisno, B.;Hidayat, A. Kinetic Study on the Esterification of Palm Fatty Acid Distillate (PFAD) Using Heterogeneous Catalyst, Materials Science and Engineering, 358, 2018.
  14. AfeeqShahid;Yousuf Jamal; Sher Jamal Khan;Jamshed Ali Khan;Bryan BoulangerEsterification Reaction Kinetics of Acetic and Oleic Acidswith Ethanol in the Presence of Amberlyst 15, King Fahd University of Petroleum & Minerals, 2017.
  15. Encinar, J. M.; Sanchez, N.; Martinez, G.; Garcia, L. Study Of Biodiesel Production From Animal Fats With High Free Fatty Acid Content, BioresourTechnol, 102:10907–14, 2016.
  16. Musa Atadashi. The Effects Of Alcohol To Oil Molar Ratios And The Type Of Alcohol On Biodiesel Production Using Transesterification Process,Egyptian Journal of Petroleum, 25, 2016.
  17. Abhishek Kundu;Anupam Mukherjee;GopinathHalder;DeepshikhaDattaA Kinetic Study on Acid Catalyzed Esterification of Free Fatty Acids in RicinusCommunis Oil for the Production of Biodiesel, International Journal of Research in Engineering and Technology,eISSN: 2319-1163, 2017.
    1. iniciusKartnaller;Ivaldo I. Junior; Adriana V.A. de Souza; Ingrid C.R. Costa; Michelle J.C. Rezende;João F. Cajaiba da Silva; Rodrigo O.M.A. de Souza.Evaluating the Kinetics of the Esterification of Oleic Acid WithHomoand Heterogeneous Catalysts Using in-Line Real-Time Infrared spectroscopy and Partial Least Squares Calibration, Journal of Molecular Catalysis B: Enzymatic, 123, 41–46, 2017.
    2. Komintarachat, C.; and Chuepeng, S. Continuous Production Of Palm Biofuel Under Supercritical Ethyl Acetate, Energy Conversion and Management, 93, 332-338, 2015.
      1. Levenspiel, Octave. Chemical Reaction Engineering. 3rded. New York: John Wiley & Sons, 1999.
Statistics
Article View: 367
PDF Download: 587