SYNTHESIS AND CHARACTERIZATION OF A NEW CATION EXCHANGER-MANGANESE (II) SILICATE DOPING WITH FE, CE, V AND W ELEMENTS AND THEIR USE FOR TREATMENT INDUSTRIAL LIQUID WASTES. | ||||
Al-Azhar Bulletin of Science | ||||
Article 25, Volume 21, Issue 2-A, December 2010, Page 345-362 PDF (532.75 K) | ||||
DOI: 10.21608/absb.2010.7386 | ||||
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Authors | ||||
I. M. EL-NAGGAR* 1; E. S. ZAKARIA1; I. M. ALI1; M. M. EL-SABBAH2; A. S. SOLIMAN2 | ||||
1Atomic Energy Authority, Hot Labs. Center, P. No. 13759, Egypt. | ||||
2Chemistry Department, Faculty of Science, Al -Azhar University, Cairo, Egypt. | ||||
Abstract | ||||
Manganese (II) silicate has been synthesized as a gel product by direct precipitation reaction. Modifying its structure by doping with iron, cerium, vanadium and tungsten elements has been carried out. These materials were characterized using X-ray, IR ,TGA-DTA and chemical stability was studied. The prepared materials show increasing in the capacities values from 2.65, 2.55, 2.22, 1.73 and 1.50 to 3.61, 3.42, 3.11, 2.68 and 2.16 (meqg-1) for Co2+, Cd2+, Cu 2+, Cs+ and Al3+, Respectively as a result of the modification by doping. pH titration data reveal monofunctional behavior. The distribution coefficients values of metal ions have been determined at different pHs. Column application was also studied. | ||||
Keywords | ||||
CATION EXCHANGER-MANGANESE (II) SILICATE; Fe, Ce, V, W ELEMENTS | ||||
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