IONIZATION OF PERLNDOPRIL PERMADIOL AND AMINEPTINE – HCL AS PHARMACEUTICAL LIGANDS AND THEIR COMPLEXES WITH DIVALENT CATIONS AND LANTHANONS. | ||||
Al-Azhar Bulletin of Science | ||||
Article 4, Volume 19, Issue 1-A, June 2008, Page 41-48 PDF (533.13 K) | ||||
Document Type: Original Article | ||||
DOI: 10.21608/absb.2008.8995 | ||||
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Authors | ||||
ADEL S. ORABI* 1; N. B. EL-ASSY2; ABD EL-GWAD M. RADI3; N. S. ABDEL-GHANY2; SAWSSAN M. ABU EL-HASSAN2 | ||||
1Department of Chemistry, Faculty of Science, Suez Canal University, Ismailia, Egypt | ||||
2Department of Chemistry, Faculty of Education, Suez Canal University, El-Arish, Egypt. | ||||
3Department of Chemistry, Faculty of Science, (Demiatta), Mansoura University, Egypt. | ||||
Abstract | ||||
Proton – constants of Per (I) and Amin (II) ligands and the formation constants of their complexes with some transition metal ions (Zn(II) and Cu(II)) and some trivalent lanthanides (Ce(III), Pr(III), and Er(III)) ions have been determined potentiometrically in aqueous methanol medium. The effect of temperature was studied at 20, 30, and 40ºC. The thermodynamic parameters (∆Hº, ∆Gº, ∆Sº) were evaluated and discussed. The formation curves for the metal complexes were obtained and the formation constants were determined. | ||||
Keywords | ||||
potentiometry, complexes; Thermodynamic | ||||
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