Adsorption of Diclofenac from Aqueous Solution Using Highly Meso porous Carbon | ||||
| Journal of Scientific Research in Science | ||||
| Article 10, Volume 37, Part 1 (Basic Sciences), February 2020, Page 146-164 PDF (1.38 MB) | ||||
| Document Type: Original Article | ||||
| DOI: 10.21608/jsrs.2020.129927 | ||||
 View on SCiNiTO | ||||
| Authors | ||||
| Nadia A. Youssef* 1; Ebtsam S. Hamza1; Seham A. Shaban2 | ||||
| 1Chemistry Department, Faculty of Women for Arts, Science and Education, Ain-Shams University, Cairo, Egypt. | ||||
| 2Egyptian Petroleum Research Institute (EPRI), Cairo, Egypt. | ||||
| Abstract | ||||
| Synthetics of mesoporous carbon (MC) from biomass including sucrose was used as the carbon resource, and eutectic salt (KCl/NaCl) as the porogen agent for the preparation of S-MC (sucrose mesopores carbons). The resultant samples were examined by means of different techniques, including thermal analysis (TGA), FTIR, transmitted electron microscopy (TEM), X-ray diffraction (XRD) and BET measurements. Investigate the efficiency of adsorption of diclofenac by highly mesopores carbons using Ultraviolet–Visible spectroscopy. The final concentrations of diclofenac were measured using Ultraviolet–Visible spectroscopy at different conditions (pH, contact time, temperature, weight of adsorbate, weight of adsorbent). | ||||
| Keywords | ||||
| diclofenac; sucrose; meso porous carbon; UV–spectroscopy | ||||
| References | ||||
|
[1] J. R .Holst, and A. I.Cooper, "Ultrahigh surface area in porous solids." Adv. Mater., 22(45):(2010) 5212-5216.
[2] M. Shiddiq , T.Ivandini and Y. Krisnandi,"Mesoporous carbon synthesis and its application for electrochemical capacitors. "( 2020) AIP Conference Proceedings, AIP Publ*89ishing LLC.,).
[3] Ľ. Pikna, M. Heželová, S.Demčáková, M.Smrčová, B.Plešingerová, M.Štefanko, M .Turáková, M.Králik, P.Puliš, and P.Lehocký, "Effect of support on activity of palladium catalysts in nitrobenzene hydrogenation." Chem. Papers, 68(5): (2014) 591-598.
[4] X. Li, H.Zhu, C.Liu, P.Yuan, Z.Lin, J.Yang, Y.Yue, Bai Z., T.Wang ,and X.Bao ,"Synthesis, modification, and application of hollow mesoporous carbon submicrospheres for adsorptive desulfurization." Ind. & Eng. Chem. Res., 57(44): (2018) 15020-15030.
[5] B.Tiryaki, E.Yagmur, A. Banford, and Z.Aktas ,"Comparison of activated carbon produced from natural biomass and equivalent chemical compositions." J.Anal. and Appl. Pyrol,105: (2014) 276-283.
[6] E.Yagmur, M. S.Tunc, A.Banford ,and Z.Aktas, "Preparation of activated carbon from autohydrolysed mixed southern hardwood." J.Anal. and Appl. Pyrol.,104: (2013) 470-478.
[7] J.Zhou, A.Luo, and Y.Zhao, "Preparation and characterisation of activated carbon from waste tea by physical activation using steam." J. the Air & Waste Manag. Assoc., 68(12): (2018) 1269-1277.
[8] N.Sych, S.Trofymenko, O.Poddubnaya, M. Tsyba, V.Sapsay, D.Klymchuk, and A.Puziy, "Porous structure and surface chemistry of phosphoric acid activated carbon from corncob." Appl. Surf. Sci., 261: (2012) 75-82.
[9] J.Wang, A.Heerwig, M. R. Lohe, M.Oschatz, L.Borchardt ,and S.Kaskel ,"Fungi-based porous carbons for CO 2 adsorption and separation." J. Mater. Chem.,22(28): (2012)13911-13913.
[10] I. I. Gurten, M.Ozmak, E.Yagmur, and Z.Aktas ,"Preparation and characterisation of activated carbon from waste tea using K2CO3." Biomass and Bioenergy,37: (2012) 73-81.
[11] M.Divino, DA. Rocha, F.Pereira Dias Viegas, H.Cristina Campos, P.Carolina Nicastro, P.Calve Fossaluzza, C.Alberto Manssour Fraga, E. J. Barreiro and C.Viegas ,"The role of natural products in the discovery of new drug candidates for the treatment of neurodegenerative disorders II: Alzheimer's disease." CNS & Neurological Disorders-Drug Targets (Formerly Current Drug Targets-CNS & Neurological Disorders), 10(2): (2011) 251-270.
[12] M. Sevilla, A. B.Fuertes and. R.Mokaya, "High density hydrogen storage in superactivated carbons from hydrothermally carbonized renewable organic materials." Energy & Environ. Sci., 4(4): (2011) 1400-1410.
[13] M. M.Alam, M. A.Hossain, M. D.Hossain, M. Johir, J.Hossen, M. S.Rahman, J. L.Zhou, A.Hasan, A. K.Karmakar and M. B.Ahmed ,"The potentiality of rice husk-derived activated carbon: From synthesis to application." Processes ,8(2): (2020)203.
[14] M.Isik, H.Sardonand D.Mecerreyes ,"Ionic liquids and cellulose: dissolution, chemical modification and preparation of new cellulosic materials." Inter. j. molec. sci. ,15(7): (2014)11922-11940.
[15] P.Maki-Arvela, T.Salmi, B.Holmbom, S.Willfor and D. Y.Murzin,"Synthesis of sugars by hydrolysis of hemicelluloses-a review." Chem. Reviews ,111(9): (2011)5638-5666.
[16] S.Shylesh, A. A.Gokhale, C. R. Ho and A. T.Bell, "Novel strategies for the production of fuels, lubricants, and chemicals from biomass." Accoun. chem. res.,50(10): (2017) 2589-2597.
[17] L. K.Shrestha, M.Thapa, R. G.Shrestha, S.Maji, R. R.Pradhananga and K.Ariga ,"Rice husk-derived high surface area nanoporous carbon materials with excellent iodine and methylene blue adsorption properties." C—J. Carbon Res. ,5(1): (2019) 10.
[18] T. P.Fellinger, R. J. White, M. M.Titirici and M.Antonietti, "Borax‐mediated formation of carbon aerogels from glucose." Adv. Functional Mater., 22(15): (2012) 3254-3260.
[19] D.Saha, Y.Li, Z.Bi, J.Chen, J. K.Keum, D. K. Hensley, H H. Grappe, M. A.Meyer III, S.Dai and M. P.Paranthaman, "Studies on supercapacitor electrode material from activated lignin-derived mesoporous carbon." Langmuir, 30(3): (2014) 900-910.
[20] M.Antonietti, N.Fechler and T.-P.Fellinger ,"Carbon aerogels and monoliths: control of porosity and nanoarchitecture via sol–gel routes." Chem. Mater. ,26(1): (2014)196-210.
[21] X.Gao, L.Wu, Z.Li, Q.Xu, W.Tian and. R.Wang ,"Preparation and characterization of high surface area activated carbon from pine wood sawdust by fast activation with H 3 PO 4 in a spouted bed." J. Mater. Cycles and Waste Manag. ,20(2): (2018) 925-936.
[22] A. S.Mestre, R. A.Pires, I.Aroso, E. M. Fernandes, M. L.Pinto, R. L.Reis, M. A.Andrade, J.Pires, S. P.Silva and A. P.Carvalho, "Activated carbons prepared from industrial pre-treated cork: Sustainable adsorbents for pharmaceutical compounds removal." Chem. Eng. J., 253: (2014) 408-417.
[23] M. Sevilla, A.Fuertes and R.Mokaya ,"Preparation and hydrogen storage capacity of highly porous activated carbon materials derived from polythiophene." Internat. j. hydrogen energy, 36(24): (2011) 15658-15663.
[24] X.Song, Y.Zhang and C.Chang, "Novel method for preparing activated carbons with high specific surface area from rice husk." Ind. & eng. chem. res.,51(46): (2012)15075-15081.
[25] Y.Xiao, H.Chen, M. Zheng, H.Dong, B.Lei and Y.Liu, "Porous carbon with ultrahigh specific surface area derived from biomass rice hull." Mater. Letters, 116: (2014) 185-187.
[26] N.Fechler, T. P.Fellinger and M.Antonietti, "“Salt templating”: a simple and sustainable pathway toward highly porous functional carbons from ionic liquids." Adv. Mater.,25(1): (2013)75-79.
[27] N.Fechler, S.-A.Wohlgemuth, P.Jäkerand. M.Antonietti ,"Salt and sugar: direct synthesis of high surface area carbon materials at low temperatures via hydrothermal carbonization of glucose under hypersaline conditions." J. Mater. Chem. A 1 ,(33): (2013)9418-9421.
[28] T.Pagketanang, A.Artnaseaw, P.Wongwicha and M.Thabuot ,"Microporous activated carbon from KOH-activation of rubber seed-shells for application in capacitor electrode." Energy Procedia, 79(2015): (2015) 651-656.
[29] J.Kaźmierczak, P.Nowicki and. R.Pietrzak ,"Sorption properties of activated carbons obtained from corn cobs by chemical and physical activation." Adsorp., 19(2-4): (2013)273-281.
[30] B. K .Hamad, "Preparation and characterization of activated carbon from oil palm shell activated by KOH." J. Pure Appl. Sci, 27: (2015) 27-38.
[31] N.Dejang, O.Somprasit and S.Chindaruksa, "A preparation of activated carbon from Macadamia shell by microwave irradiation activation." Energy Procedia, 79: (2015) 727-732.
[32] J. N .Nsami, and J. K.Mbadcam ,"The Adsorption Efficiency of Chemically Prepared Activated Carbon from Cola Nut Shells by ZnCl 2 on Methylene Blue." J. chem., (2013).
[33] X. Liu ,and M.Antonietti ,"Molten salt activation for synthesis of porous carbon nanostructures and carbon sheets." Carbon, 69: (2014)460-466.
[34] X.Liu, N.Fechler and M.Antonietti ,"Salt melt synthesis of ceramics, semiconductors and carbon nanostructures." Chem. Soc. Reviews,42(21): (2013) 8237-8265.
[35] X.Liu, C.Giordano and M.Antonietti, "A Facile Molten‐Salt Route to Graphene Synthesis." Small, 10(1): (2014)193-200.
[36] R.Ruiz Rosas, F. J.García-Mateos, M. d. C.Gutiérrez, J.Rodríguez-Mirasoland T. Cordero ,"About the Role of Porosity and Surface Chemistry of Phosphorus-Containing Activated Carbons in the Removal of Micropollutants." Frontiers in Mater. ,6: (2019)134.
[37] J. N. Nsami, and J. K.Mbadcam ,"The Adsorption Efficiency of Chemically Prepared Activated Carbon from Cola Nut Shells by ZnCl 2 on Methylene Blue." J. chem., (2013).
[38] D.Lin, Y.Huang, Y.Yang, X.Long, W.Qin, H.Chen, Q. Zhang, Z. Wu, S.Li and D.Wu,"Preparation and Characterization of Highly Ordered Mercapto-Modified Bridged Silsesquioxane for Removing Ammonia-Nitrogen from Water." Polymers ,10(8): (2018) 819.
[39] S.Zhang, M.Zheng, Z.Lin, N.Li, Y.Liu, B.Zhao, H.Pang, J.Cao, P.He and Y.Shi, "Activated carbon with ultrahigh specific surface area synthesized from natural plant material for lithium–sulfur batteries." J. Mater. Chem., A 2(38): (2014) 15889-15896.
| ||||
|
Statistics Article View: 293 PDF Download: 241 |
||||
