Assessment of Heavy Metals Immobilization in Artificially Contaminated Soils Using some Local Amendments | ||||
| Egyptian Journal of Soil Science | ||||
| Article 6, Volume 53, Issue 3, September 2013, Page 379-394 PDF (567.86 K) | ||||
| Document Type: Original Article | ||||
| DOI: 10.21608/ejss.2013.174 | ||||
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| Abstract | ||||
| T HREE alluvial soil samples of different textures were artificially polluted with chloride solutions of Cd, Pb, Co and chromate solution for Cr. The aqua-regia extracted concentration ranges in the artificially polluted soils from1134-1489 mg.kg−1 for Pb, 854-938 for Cr, 166-346 for Co and 44 – 54 mg.kg−1 for Cd. The aqua-regia extracted metals were the highest in the spiked clay soil due to its high adsorption capacity. Rock phosphate (RP), lime-stone (LS) and Portland- cement (Cem) were mixed with the spiked soils at 1% and 2% rates (w/w) and incubated at 30 ˚C for 2, 7, 14, 30, 60, 150 and 360 days. The extracted DTPA metals significantly decreased with different magnitudes with increasing the incubation period accompanied by increases in both pH and EC. The data showed that cement (Cem.) treatment dropped the DTPA-Pb from approximately 1000 to 400 mg.kg−1 in all the studied soils (60% decrease) in the first 2 months while it gradually decreased from 400 to 200 mg.kg−1, (20% decrease) in the next 10 months. Limestone (LS) and rock phosphate (RP) materials were relatively less effective in lowering DTPA-Pb after 12 months of incubation. The data showed also that cement (Cem) treatment was the most effective one in lowering DTPA-Cd by 60% as compared to the un-amended soils after 12 months of soil incubation. Extractable DTPA-Co and Cr showed consistent decreases with time down to nearly 50% of un-amended soils due to the effect of the added amendments after 12 months of incubation with superior reductions for the cement treatment in all the investigated soils. The statistical analysis confirmed that in all the studied metals and treatment, cement treatment (Cem) was significantly the most effective in lowering the DTPA extracted metals as indicated by LSD test. It was found that up to 73% and 57% of the applied Pb and Cd, respectively, were fixed by only 1% cement. However, the present study showed that from the practical and economic points of view, that 1% Cement was the best treatment to immobilize Pb and Cd in all the artificially polluted soils. | ||||
| Keywords | ||||
| Heavy metals; Immobilization efficiency; Rock Phosphate; Portland Cement; Lime-stone | ||||
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